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W-Nb-O oxides with tunable acid properties as efficient catalysts for the transformation of biomass-derived oxygenates in aqueous systems

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W-Nb-O oxides with tunable acid properties as efficient catalysts for the transformation of biomass-derived oxygenates in aqueous systems

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dc.contributor.author Delgado-Muñoz, Daniel es_ES
dc.contributor.author Fernández-Arroyo, Alberto es_ES
dc.contributor.author Domine, Marcelo Eduardo es_ES
dc.contributor.author García-González, Ester es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2020-11-11T04:32:21Z
dc.date.available 2020-11-11T04:32:21Z
dc.date.issued 2019-06-21 es_ES
dc.identifier.issn 2044-4753 es_ES
dc.identifier.uri http://hdl.handle.net/10251/154804
dc.description.abstract [EN] W-Nb-O oxide bronzes, prepared hydrothermally, have been characterized and studied as catalysts for both the gas-phase dehydration of glycerol and the liquid-phase selective condensation of light oxygenates derived from primary treatments of biomass (a mixture containing acetic acid, ethanol, propanal, hydroxyacetone and water). By controlling the nominal composition of the catalysts, it is possible to tune their textural and acid properties (concentration and nature of acid sites) to selectively produce acrolein from glycerol or C-5-C-10 hydrocarbons (with low O contents and with high yields) from light oxygenates. Interestingly, these catalysts are stable when working in gas phase reactions and they are re-usable, with high resistance to leaching, when working in aqueous media. es_ES
dc.description.sponsorship Financial support by the Spanish Government (CTQ-2015-68951-C3-1, CTQ-2015-67592, MAT2016-78362-C4-4-R and SEV-2016-0683) and Generalitat Valenciana (GVA, PROMETEO/2018/006) is gratefully acknowledged. A. F.-A. and D. D. thank the "La Caixa-Severo Ochoa" Foundation and Severo Ochoa Excellence Program (SVP-2016-0683), respectively, for their fellowships. The authors thank the ICTS Centro Nacional de Microscopia Electronica (UCM) for instrumental facilities. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science & Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject W-Nb-O oxide catalyst es_ES
dc.subject Acid properties es_ES
dc.subject Transformation of biomass-derived oxygenates es_ES
dc.subject Aqueous phase es_ES
dc.title W-Nb-O oxides with tunable acid properties as efficient catalysts for the transformation of biomass-derived oxygenates in aqueous systems es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c9cy00367c es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2018%2F006/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-78362-C4-4-R/ES/MATERIALES PARA BATERIAS DE LITIO, POST LITIO Y PILAS DE COMBUSTIBLE: DEL LABORATORIO AL PROTOTIPO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099668-B-C21/ES/VALORIZACION DE CO2: CAPTURA, Y TRANSFORMACION CATALITICA PARA ALMACENAMIENTO DE ENERGIA, COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-67592-P/ES/VALORIZACION DE COMPUESTO OXIGENADOS PRESENTES EN FRACCIONES ACUOSAS DERIVADAS DE BIOMASA EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Delgado-Muñoz, D.; Fernández-Arroyo, A.; Domine, ME.; García-González, E.; López Nieto, JM. (2019). W-Nb-O oxides with tunable acid properties as efficient catalysts for the transformation of biomass-derived oxygenates in aqueous systems. Catalysis Science & Technology. 9(12):3126-3136. https://doi.org/10.1039/c9cy00367c es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c9cy00367c es_ES
dc.description.upvformatpinicio 3126 es_ES
dc.description.upvformatpfin 3136 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 12 es_ES
dc.relation.pasarela S\405396 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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