Abstract Atmospheric particles can come from natural or anthropological sources. They can produce a series of negative effects on human health, environment, climate, visibility, materials of construction etc. widely studied and documented. In the province of Castellón, in an area of approximately 300 km2 there are located more than 200 companies involved in the ceramic sector. 94% of Spanish ceramic production is concentrated in this area, accounting for 43% of the whole European production. Since 2005 there is an agreement between the City of Alcora and the University Jaume I of Castellón in order to track pollution in two different locations, one in the industrial area and one in the city center. This tracking refers to the tracking of both levels, PM10 and PM2,5 and the chemical composition (contents of nickel, cadmium, arsenic and lead in PM10 and PM2,5) of the material sampled. The experience and data obtained from that agreement led to set as the central theme of this work the study of pollution levels and the chemical composition regarding regulated elements (Ni, Cd, As y Pb) of atmospheric particles on both stations of Alcora, its evolution between 2006 and 2010 and its correspondence and degree of law compliance with the levels measured by the Conselleria in the rest of locations of the ceramic cluster during the same period. Moreover, we have selected a number of samples of PM10 and PM2,5 in the industrial and urban stations between 2006 and 2010 and they have been analyzed to determine their chemical composition. The use of a receptor model (PCA) from the results of the analysis has resulted in the identification of possible sources, both natural and anthropogenic. From the hourly data of different stations that the Conselleria has in the province of Castellón, the model of independent component analysis (ICA) has been applied in order to assess the sources of these pollutants. To obtain an estimate of external costs due to pollution from the ceramic industry in Alcora the ExternE methodology has been applied. We also estimated the profitability of environmental investments in the ceramic industries of Alcora by comparing the actual external costs with those that would be present once all the investments included in the plan to improve the air quality of the Generalitat Valenciana are accomplished.