Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley-VCH Verlag, 2011-04-14)
[EN] Aerobic oxidation of cyclooctane to its corresponding ol/one mixture at atmospheric pressure and in the liquid phase is efficiently promoted by an Fe(BTC) (BTC=1,3,5-benzenetricarboxylate) metal-organic framework, ...
Dhakshinamoorthy, Amarajothi; García Gómez, Hermenegildo(Royal Society of Chemistry, 2012)
[EN] The present review describes the use of metal-organic frameworks (MOFs) as porous matrices to embed metal nanoparticles (MNPs) and occasionally metal oxide clusters, which are subsequently used as heterogeneous ...
Dhakshinamoorthy, Amarajothi; Asiri, Abdullah M.; García Gómez, Hermenegildo(Royal Society of Chemistry, 2014)
[EN] Metal–organic frameworks (MOFs) having a large surface area and porosity as well as a high density of transition metals are increasingly used as heterogeneous catalysts for organic reactions. However, one of the main ...
Dhakshinamoorthy, Amarajothi; Asiri, Abdullah M.; García Gómez, Hermenegildo(Elsevier, 2016-06-02)
[EN] A well known copper based-metal organic framework (MOF), namely Cu-3(BTC)(2), is a suitable heterogeneous catalyst to promote the oxidative room-temperature hydroxylation of arylboronic acids to the corresponding ...
DHAKSHINAMOORTHY, AMARAJOTHI; Asiri, Abdullah; García Gómez, Hermenegildo(American Chemical Society, 2019-02-01)
[EN] Cross-coupling reactions catalyzed by transition metals are currently among the most widely used transformations in organic synthesis. In most of these reactions, the coupling involves the reaction of two complementary ...
Navalón Oltra, Sergio; Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Elsevier, 2016)
[EN] The catalytic activity of metal nanoparticles (MNPs) is highly dependent on the nature of the support. In addition to the role of particle size stabilization in decreasing the spontaneous growth of small MNPs, the ...
Dhakshinamoorthy, Amarajothi; Opanasenko, Maksym; Cejka, Jiri; García Gómez, Hermenegildo(Royal Society of Chemistry, 2013)
[EN] This review focuses on the use of metal organic frameworks (MOFs) as catalysts for the synthesis of fine chemicals. While petrochemistry is characterized by gas phase reactions, in which MOFs cannot compete with robust ...
Dhakshinamoorthy, Amarajothi; Navalón Oltra, Sergio; Asiri, Abdullah M.; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2020-01-04)
[EN] Metal organic frameworks (MOFs) are widely used as solid catalysts in the liquid phase under batch mode conditions. Moving towards the development of industrial processes, data of the performance of MOFs under continuous ...
Dhakshinamoorthy, Amarajothi; Navalón Oltra, Sergio; Corma Canós, Avelino; García Gómez, Hermenegildo(Royal Society of Chemistry, 2012-11)
[EN] The shortage of fossil fuels and the need to find alternative renewable and sustainable fuels for transportation are triggering an increasing interest in the photocatalytic reduction of CO 2. In this review, we have ...
Dhakshinamoorthy, Amarajothi; Navalón Oltra, Sergio; Sempere Aracil, David; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Royal Society of Chemistry, 2013)
Copper nanoparticles (Cu NPs) supported on diamond nanoparticles (D NPs) previously purified by Fenton treatment (Cu/D) followed by annealing with hydrogen (Cu/DH) are highly efficient and reusable heterogeneous catalysts ...