Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(American Chemical Society, 2011)
[EN] Cu3 (BTC)2 (BTC: 1,3,5-benzenetricarboxylate) combined with TEMPO as cocatalyst is an e¿ective and reusable heterogeneous catalyst to e¿ect the aerobic oxidation of benzylic alcohols in acetonitrile to the corresponding ...
Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Elsevier, 2012)
[EN] Iron metal organic framework [Fe(BTC)) loaded with N-hydroxyphthalimide (NHPI) promotes the aerobic oxidation of (cyclo)alkenes to give variable percentages of allylic oxidation products and the corresponding epoxide, ...
Amarajothi ., Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(American Chemical Society, 2011)
[EN] Aerobic oxidation of a series of styrenes to benzaldehyde,
styrene oxide, and derivatives has been performed with N-hydroxyphthalimide loaded on Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate) under
di¿erent reaction ...
After purification by Fenton treatment, commercial diamond nanoparticles (NPs) are a suitable solid support for the deposition of Cu nanoparticles. Heating at 5008C under hydrogen proved to be a convenient annealing process ...
Amarajothi, Dhakshinamoorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Royal Society of Chemistry, 2012)
Metal¿organic frameworks (MOFs) are porous crystalline materials that have promising
applications as heterogeneous catalysts. After describing the composition, textural properties and
crystal structure of four commercially ...
Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; Horcajada Campos, Patricia; Gibson, Emma; Vishnuvarthan, Muthusamy; Vimont, Alexandre; Grenèche, Jean-Marc; Serre, Christian; Daturi, Marco; García Gómez, Hermenegildo(American Chemical Society, 2012-08)
[EN] Two porous iron trimesates, namely, commercial Basolite F300 (Fe(BTC); BTC = 1,3,5-benzenetricarboxylate) with unknown structure and synthetic MIL-100(Fe) (MIL stands for Material of Institut Lavoisier) of welldefined ...
Dhakshinamoorthy, Amarajothi; He, Jinbao; Franconetti, Antonio; Asiri, Abdullah M.; Primo Arnau, Ana Maria; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2018-03-21)
[EN] A series of defective graphenes containing or not containing N, B, S and other heteroatoms exhibited general activity as metal-free catalysts for the hydrogenation of C=C double bonds by hydrazine in the presence of ...
Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; Dhakshinamoorthy, Amarajothi; García Gómez, Hermenegildo(MDPI AG, 2019-09-01)
[EN] Nitro group reduction is a reaction of a considerable importance for the preparation of bulk chemicals and in organic synthesis. There are reports in the literature showing that incorporation of metal nanoparticles ...
Amarajothi, Dhakshinamoorthy; Alvaro Rodríguez, Maria Mercedes; Concepción Heydorn, Patricia; Fornes Seguí, Vicente; García Gómez, Hermenegildo(Royal Society of Chemistry, 2012)
The minute amount of hydrogen sulfate groups introduced into
the graphene oxide (GO) obtained by Hummers oxidation of
graphite renders this material as a highly e¿cient, recyclable
acid catalyst for the ring opening of ...
[EN] Graphene oxide obtained through the standard Hummers oxidation
of graphite and subsequent exfoliation promotes acetalization
of aldehydes in methanol. It is a highly efficient reusable
heterogeneous catalyst because ...
Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; Chevreau, Hubert; Horcajada Campos, Patricia; Devic, Thomas; Serre, Christian; García Gómez, Hermenegildo(Royal Society of Chemistry, 2012)
[EN] A series of Fe3+-containing porous metal-organic frameworks (MOFs), including the commercial iron trimesate Basolite F-300 or Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate) and the synthetic iron terephthalate MIL-88B ...
Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Royal Society of Chemistry, 2011)
In this Perspective, we describe the use of metal-organic frameworks (MOFs) as heterogeneous catalysts for oxidations using hydroperoxides or molecular oxygen. These two types of oxidants fulfill the requirements of green ...
Dhakshinamoorthy, Amarajothi; Asiri, Abdullah M.; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2016)
[EN] Metal organic frameworks (MOFs) are among the most studied heterogeneous catalysts that have been applied to promote a wide range of reactions. Most of the initial studies on the catalytic activity of MOFs were based ...
Espinosa-López, Juan Carlos; Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; Dhakshinamoorthy, Amarajothi; García Gómez, Hermenegildo(American Chemical Society, 2018)
[EN] A series of active carbons with or without chemical oxidation by nitric acid have been prepared, and their activity was evaluated as metal-free catalysts for the C=C double bond hydrogenation using hydrazine as reducing ...