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Browsing by Author "Real, José A."

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Meltable Spin Transition Molecular Materials with Tunable Tc and Hysteresis Loop Width

Romero-Morcillo, Tania; Seredyuk, Maksym; Muñoz Roca, María del Carmen; Real, José A. (Wiley, 2015-12)

Herein, we report a way to achieve abrupt high-spin to low-spin transition with controllable transition temperature and hysteresis width, relying not on solid-state cooperative interactions, but utilizing coherency ...
Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworks

Romero Morcillo, Tania; De la Pinta, Noelia; Callejo, Lorena M.; Piñeiro López, Lucía; Muñoz Roca, María del Carmen; Madariaga, Gotzon; Ferrer, Sacramento; Breczewski, Tomasz; Cortés, Roberto; Real, José A. (Wiley, 2015-08-17)

[Fe(tvp)(2)(NCS)(2)] (1) (tvp=trans-(4,4-vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two-dimensional grids. This uncommon supramolecular conformation defines square-sectional ...
Single-Crystal X-Ray Diffraction Study of Pressure and Temperature-Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework

Turner, Gemma F.; Campbell, Fallyn; Moggach, Stephen A.; Parsons, Simon; Goeta, Andrés E.; Muñoz Roca, María Del Carmen; Real, José A. (John Wiley & Sons, 2020-02-17)

[EN] High-pressure single-crystal X-ray diffraction has been used to trap both the low-spin (LS) and high-spin (HS) states of the iron(II) Hofmann spin crossover framework, [FeII (pdm)(H2 O)[Ag(CN)2 ]2·H2 O, under identical ...
Spin crossover in iron(II) complexes with ferrocene-bearing triazole-pyridine ligands

Romero Morcillo, Tania; Valverde Muñoz, Francisco Javier; Piñeiro López, Lucía; Muñoz Roca, María del Carmen; Romero, Tomás; Molina, Pedro; Real, José A. (Royal Society of Chemistry, 2015)

In the search for new multifunctional spin crossover molecular materials, here we describe the synthesis, crystal structures and magnetic and photomagnetic properties of the complexes trans-[Fe(Fctzpy)2(NCX)2]·CHCl3 where ...
Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals

Ortega-Villar, Norma; Muñoz Roca, María del Carmen; Real, José A. (MDPI, 2016-03)

[EN] This review provides an up to date survey of a singular class of iron(II) spin crossover (SCO) molecular materials that undergo high-spin (HS) Ø low-spin (LS) phase transitions accompanied by crystallographic symmetry ...
Two- and one-step cooperative spin transitions in Hofmann-like clathrates with enhanced loading capacity

Piñeiro-López, Lucía; Seredyuk, Maksym; Muñoz Roca, María del Carmen; Real, José A. (Royal Society of Chemistry, 2014)

Structural, magnetic, calorimetric and Mo¨ssbauer studies of the cooperative spin crossover naphthalene and nitrobenzene clathrates of the novel FeII Hofmann-like porous metal–organic framework {Fe(bpb)[Pt(CN)4]}2Guest ...

Now showing items 1-6 of 6

Browsing by Author "Real, José A."

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Browsing by Author "Real, José A."