Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(American Chemical Society, 2011)
[EN] Cu3 (BTC)2 (BTC: 1,3,5-benzenetricarboxylate) combined with TEMPO as cocatalyst is an e¿ective and reusable heterogeneous catalyst to e¿ect the aerobic oxidation of benzylic alcohols in acetonitrile to the corresponding ...
Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Elsevier, 2012)
[EN] Iron metal organic framework [Fe(BTC)) loaded with N-hydroxyphthalimide (NHPI) promotes the aerobic oxidation of (cyclo)alkenes to give variable percentages of allylic oxidation products and the corresponding epoxide, ...
Amarajothi ., Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(American Chemical Society, 2011)
[EN] Aerobic oxidation of a series of styrenes to benzaldehyde,
styrene oxide, and derivatives has been performed with N-hydroxyphthalimide loaded on Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate) under
di¿erent reaction ...
After purification by Fenton treatment, commercial diamond nanoparticles (NPs) are a suitable solid support for the deposition of Cu nanoparticles. Heating at 5008C under hydrogen proved to be a convenient annealing process ...
Buaki-Sogo, Mireia; Serra, Marco; Primo Arnau, Ana María; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(WILEY-VCH Verlag GmbH & Co. KGaA,, 2012)
[EN] A simple and reliable procedure to prepare TiO2 and Au/TiO2 samples with high photocatalytic activity for hydrogen generation from water/methanol mixtures is reported, which uses natural alginate as the templating ...
Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Taylor & Francis, 2011)
In the present work we fractioned the effluent water from an urban sewage treatment plant (USTP) of Ribarroja (Valencia, Spain) using the conventional protocol based on DAX8 and XAD4 resins. The fractions were analyzed by ...
Buaki Sogo, Mireia(Universitat Politècnica de València, 2012-11-16)
El auto-ensamblaje donde debido a la interacción con el disolvente moléculas de un compuesto anfifílico se asocian espontáneamente es un proceso general que puede servir para la preparación de entidades supramoleculares ...
Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley-VCH Verlag, 2011-04-14)
[EN] Aerobic oxidation of cyclooctane to its corresponding ol/one mixture at atmospheric pressure and in the liquid phase is efficiently promoted by an Fe(BTC) (BTC=1,3,5-benzenetricarboxylate) metal-organic framework, ...
Rojas, Santiago; Gispert, Juan D.; Martín González, Roberto; Abad, Sergio; Menchón, Cristina; Pareto, Deborah; Víctor, Víctor M.; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo; Herance, J. Raúl(American Chemical Society, 2011)
[EN] Nanoparticles have been proposed for several biomedical applications; however,
in vivo biodistribution studies to con¿rm their potential are scarce. Nanodiamonds are carbon
nanoparticles that have been recently ...
Cubas Pardo, Alejandro(Universitat Politècnica de València, 2016-07-15)
[ES] En el presente Trabajo Fin de Grado, se pretende caracterizar fotofísicamente un tipo particular de
material reticulado metal-orgánico, el UiO-66-NH2(Zr) sustituido parcialmente por Titanio y estudiar
sus propiedades ...
Garcia Pla, Alberto(Universitat Politècnica de València, 2017-09-21)
This final degree paper is based on the photochemical characterization of MIL-125 (TI) MOFs in order to study the photogeneration of the charge separation state for its possible application as photoactive material in ...
Navalón Oltra, Sergio; Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(American Chemical Society, 2014-06-25)
[EN] Carbon materials derived from biomass are considered paradigmatic examples of sustainability.6,7 Other factors besides sustainability that may also favor carbon-based versus inorganic materials as catalysts are economic ...
Mikami, Yusuke; Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Royal Society of Chemistry, 2013)
[EN] This article reviews some of the compelling evidence showing that colloidal gold nanoparticles without any solid support exhibit intrinsic catalytic activity for some of the typical gold-catalyzed reactions including ...
Bernat-Quesada, Francisco; Espinosa-López, Juan Carlos; Barbera, Vincenzina; Alvaro Rodríguez, Maria Mercedes; Galimberti, Maurizio; Navalón Oltra, Sergio; García Gómez, Hermenegildo(American Chemical Society, 2019-10-21)
[EN] This work reports the catalytic ozonation activity of high surface area graphite materials selectively functionalized at the edges with hydroxyl groups. The graphite-based catalyst shows higher activity than the parent ...
Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; Concepción Heydorn, Patricia; García Gómez, Hermenegildo(Elsevier, 2011-06-10)
In contrast to Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate), the crystal structure of Cu3(BTC)2, a commercial metal organic framework widely used as solid catalyst, collapses when contacted with thiols under mild reaction ...
Moussaif, Ahmed; Martín González, Roberto; Ramli, Y.; ZNIBER, RACHID; ACHOUR, REDOUANE; El Ghoul, M.; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Editura Academiei Romane, 2011)
[EN] Preformed chiral bis(oxazoline)copper complex having a 4-aminobutyl linker in the meso carbon has been covalently attached to
single wall carbon nanotubes (1 µm average length) through the carboxylic acid groups and ...
Amarajothi, Dhakshinamoorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Royal Society of Chemistry, 2012)
Metal¿organic frameworks (MOFs) are porous crystalline materials that have promising
applications as heterogeneous catalysts. After describing the composition, textural properties and
crystal structure of four commercially ...
Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; Horcajada Campos, Patricia; Gibson, Emma; Vishnuvarthan, Muthusamy; Vimont, Alexandre; Grenèche, Jean-Marc; Serre, Christian; Daturi, Marco; García Gómez, Hermenegildo(American Chemical Society, 2012-08)
[EN] Two porous iron trimesates, namely, commercial Basolite F300 (Fe(BTC); BTC = 1,3,5-benzenetricarboxylate) with unknown structure and synthetic MIL-100(Fe) (MIL stands for Material of Institut Lavoisier) of welldefined ...
Espinosa-López, Juan Carlos; Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2016)
[EN] A series of catalysts consisting of Cu nanoparticles (NPs) supported on diamond nanoparticles (D) were obtained by polyol reduction of CuNO3)(2) in the presence of D. The best performing Cu/D catalyst was obtained ...
Blandez Barradas, Juan Francisco; Primo Arnau, Ana María; Asiri, Abdullah; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley-VCH Verlag, 2014-11-10)
[EN] Copper nanoparticles (NPs) supported on a series of
undoped and doped graphene materials (Gs) have been
obtained by pyrolysis of alginate or chitosan biopolymers,
modified or not with boric acid, containing Cu2+ ...