Zhang, Daopeng; Trzop, Elzbieta; Valverde-Muñoz, Francisco J.; Piñeiro-López, Lucía; Muñoz Roca, María del Carmen; Collet, Eric; Real, Jose A.(American Chemical Society, 2017)
[EN] Competition between spin-crossover and structural ligand ordering is identified as responsible for multistability and generation of six different phases in a rigid two-dimensional coordination polymer formulated ...
Trzop, Elzbieta; Zhang, Daopeng; Piñeiro López, Lucia; Valverde Muñoz, Francisco J.; Muñoz Roca, María del Carmen; Palatinus, Lukas; Guerin, Laurent; Cailleau, Hervé; Real, José Antonio; Collet, Eric(Wiley, 2016)
[EN] The unprecedented bimetallic 2D coordination polymer {Fe[(Hg(SCN)3)2](4,4’-bipy)2}n exhibits a thermal
high-spin (HS)$low-spin (LS) staircase-like conversion characterized by a multi-step dependence of the HS ...
Piñeiro-López, Lucía; Valverde-Muñoz, Francisco Javier; Trzop, Elzbieta; Muñoz Roca, María Del Carmen; Seredyuk, Maksym; Castells-Gil, Javier; da Silva, Iván; Marti-Gastaldo, Carlos; Collet, Eric; Real, José Antonio(The Royal Society of Chemistry, 2021-01-28)
[EN] A binary reversible switch between low-temperature multi-step spin crossover (SCO), through the evolution of the population gamma(HS)(T) with high-spin (HS)-low-spin (LS) sequence: HS1LS0 (state 1) <-> HS2/3LS1/3 ...