Sastre Calabuig, Francesc(Universitat Politècnica de València, 2013-09-02)
En el contexto de desarrollar combustibles alternativos para transporte, en la presente tésis doctoral se describen métodos de activación fotocatalíticos que permiten la conversión de metano y etano en alcoholes por ...
Juárez Marín, Raquel; Corma Canós, Avelino; García Gómez, Hermenegildo(International Union of Pure and Applied Chemistry, 2011-09-19)
Aliphatic amines react sluggishly with dimethyl carbonate (DMC) to give a mixture
of N-methylation and carbamoylation. Nanoparticulated ceria as catalyst increases, in
general, conversion and selectivity toward carbamoylation. ...
Sastre Calabuig, Francesc(Universitat Politècnica de València, 2012-01-24)
La Adición de Michael de los compuestos activos de metileno para la obtención de compuestos carbonílicos alfa, beta-insaturados es una reacción general empleada en síntesis orgánica. En el presente trabajo se ha encontrado ...
Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(American Chemical Society, 2011)
[EN] Cu3 (BTC)2 (BTC: 1,3,5-benzenetricarboxylate) combined with TEMPO as cocatalyst is an e¿ective and reusable heterogeneous catalyst to e¿ect the aerobic oxidation of benzylic alcohols in acetonitrile to the corresponding ...
Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Elsevier, 2012)
[EN] Iron metal organic framework [Fe(BTC)) loaded with N-hydroxyphthalimide (NHPI) promotes the aerobic oxidation of (cyclo)alkenes to give variable percentages of allylic oxidation products and the corresponding epoxide, ...
Amarajothi ., Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(American Chemical Society, 2011)
[EN] Aerobic oxidation of a series of styrenes to benzaldehyde,
styrene oxide, and derivatives has been performed with N-hydroxyphthalimide loaded on Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate) under
di¿erent reaction ...
Taketoshi, Ayako; Concepción Heydorn, Patricia; García Gómez, Hermenegildo; Corma Canós, Avelino; Haruta, Masatake(Chemical Society of Japan, 2013-12-15)
Although selective oxidation of sulfides to sulfoxides with molecular oxygen is a difficult reaction due to the overoxidation to sulfone, manganese oxides were found to catalyze the aerobic oxidation of sulfides to sulfoxides ...
After purification by Fenton treatment, commercial diamond nanoparticles (NPs) are a suitable solid support for the deposition of Cu nanoparticles. Heating at 5008C under hydrogen proved to be a convenient annealing process ...
[EN] Two for one gold: Factors governing the formation of isolable digold(I) ó,ð-acetylide complexes are given (see scheme), indicating the general tendency of phosphine AuI precatalysts to form this type of complexes, ...
Buaki-Sogo, Mireia; Serra, Marco; Primo Arnau, Ana María; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(WILEY-VCH Verlag GmbH & Co. KGaA,, 2012)
[EN] A simple and reliable procedure to prepare TiO2 and Au/TiO2 samples with high photocatalytic activity for hydrogen generation from water/methanol mixtures is reported, which uses natural alginate as the templating ...
Garcia-Mulero, Ana; Asiri, Abdullah M; Albero-Sancho, Josep; Primo Arnau, Ana Maria; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2022-08-18)
[EN] Microporous graphitic carbon (mp-C) derived from the pyrolysis of alpha-, beta-, and gamma-cyclodextrins exhibited photocatalytic activity in CO2-saturated acetonitrile-water upon irradiation with UV-Vis light and in ...
Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; Asiri, Abdullah M.; García Gómez, Hermenegildo(MDPI AG, 2021-06)
[EN] Cu-3(BTC)(2) (BTC: 1,3,5-benzenetricarboxylate) as a heterogeneous catalyst in the presence of cesium carbonate as a base is reported for the borylation of alpha,beta-conjugated enones by bis(pinacolato)diboron ...
Gutiérrez-Carcedo, Patricia; Navalón Oltra, Sergio; Simó, Rafael; Setoain, Xavier; Aparicio-Gómez, Carolina; Abasolo, Ibane; Victor, Victor Manuel; García Gómez, Hermenegildo; Herance, José Raúl(MDPI AG, 2020-04)
[EN] Ceria nanoparticles are cell compatible antioxidants whose activity can be enhanced by gold deposition and by surface functionalization with positive triphenylphosphonium units to selectively target the mitochondria. ...
Trandafir, M. M.; Pop, L.; Hadade, N. D.; Florea, M.; Neatu, F.; Teodorescu, C. M.; Duraki, B.; van Bokhoven, J. A.; Grosu, I.; Parvulescu, Vasile I.; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2016)
[EN] A bimodal (micro/mesoporous) COF was synthesized by coupling tetrakis-1,3,5,7-(4'-iodophenyl) adamantane with 4,4'-diethynylbiphenyl following a Sonogashira protocol. The COF preparation strategy led, however, to the ...
Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Taylor & Francis, 2011)
In the present work we fractioned the effluent water from an urban sewage treatment plant (USTP) of Ribarroja (Valencia, Spain) using the conventional protocol based on DAX8 and XAD4 resins. The fractions were analyzed by ...
Castellanos, Sonia; Sai Sankar Gupta, Karthick Babu; Pustovarenko, Alexey; Dikhtiarenko, Alla; Nasalevich, Maxim; Atienzar Corvillo, Pedro Enrique; García Gómez, Hermenegildo; Gascon, Jorge; Kapteijn, Freek(Wiley-VCH Verlag, 2015-10)
Incorporation of new functionalities into metal-organic frameworks (MOFs) by post-synthetic modification is a most attractive strategy for attaining the desired properties without risking destruction of the crystalline ...
Shamzhy, Mariya V.; Opanasenko, Maksym V.; García Gómez, Hermenegildo; Cejka, Jiri(Elsevier, 2015-01-15)
The catalytic behavior of metal-organic frameworks of different structures (Fe(BTC), MIL-100(Fe), MIL-100(Cr) and Cu-3(BTC)(2)) was investigated in annulation reaction between 2-methyl-3-buten-2-ol and phenols differing ...
Buaki Sogo, Mireia(Universitat Politècnica de València, 2012-11-16)
El auto-ensamblaje donde debido a la interacción con el disolvente moléculas de un compuesto anfifílico se asocian espontáneamente es un proceso general que puede servir para la preparación de entidades supramoleculares ...
García-Baldoví, Alberto; Peng, Lu; Santiago-Portillo, Andrea; Asiri, Abdullah M.; Primo Arnau, Ana Maria; García Gómez, Hermenegildo(American Chemical Society, 2022-07-25)
[EN] Small Fe-Cu nanoparticles (NPs) (about 1 nm) supported at a high loading (over 10 wt %) on N-doped graphitic carbon have been prepared in a single pyrolytic step from chitosan adsorbing Cu2+ and Fe2+ salts. The presence ...
Esteve-Adell, Iván; Crapart, Bertrand; Primo Arnau, Ana María; Serp, Philippe; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2017)
[EN] Boron-doped graphene obtained by pyrolysis at 900 degrees C of the boric acid ester of alginate was found to be the most active graphene among a series of doped and co-doped graphenes to promote the aqueous phase ...