[EN] Two for one gold: Factors governing the formation of isolable digold(I) ó,ð-acetylide complexes are given (see scheme), indicating the general tendency of phosphine AuI precatalysts to form this type of complexes, ...
[EN] Cationic and neutral silver(I)-L complexes (L = Buchwald-type biaryl phosphanes) with nitrogen co-ligands or organosulfonate counter ions have been synthesised and characterised through their structural and spectroscopic ...
[EN] Cationic Cu L complexes (L=Buchwald-type phosphane) with N co-ligands have been characterised by structural and spectroscopic properties. These copper(I) complexes are extremely active catalysts, far more active than ...
[EN] Alkene hydrosilylation is typically performed with Pt catalysts, but inexpensive base-metal catalysts would be preferred. Here, we report a simple method for the use of air-stable cobalt catalysts for anti-Markovnikov ...
[EN] A novel family of dipropargylamines has been synthesized in one pot through a double catalytic A3-coupling of five component. Several reactions of LAu-amine complexes with organic reagents were studied and followed ...
Grirrane, Abdessamad; García Gómez, Hermenegildo; Álvarez, Eleuterio(Beilstein-Institut, 2013-07-22)
In the context of palladium-catalyzed guanylation of anilines herein, we have been able to characterize and isolate bis(anilino) and
bis(guanidino)Pd(II) complexes using reaction conditions under which stoichiometric ...
Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley-VCH Verlag, 2013-12)
[EN] Phosphine, palladacycle, and N-heterocyclic carbene palladium complexes are highly active homogeneous catalysts that can promote a wide range of CC and CN cross-coupling reactions. An evolution from homogeneous catalysis ...
[EN] Tremorine and precursors of gemini surfactants were synthesised in a one-pot, three-step, double-catalytic A3 coupling reaction and characterised by structural and spectroscopic methods. The cationic [Au-I(L1)]SbF6 ...
[EN] The cationic complex [(JohnPhos-Au)(3)(acetylide)][SbF6] (JohnPhos=(2-biphenyl)di-tert-butylphosphine, L1) has been characterised structurally and features an acetylide-trigold(I)-JohnPhos system; the trinuclear-acetylide ...