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Browsing by Subject "Nitrosyl complexes"

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Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex

Piñeiro López, Lucía; Ortega Villar, Norma; Muñoz Roca, María del Carmen; Molnar, Gabor; Cirera, Jordi; Moreno Esparza, Rafael; Ugalde Saldivar, Victor M.; Bousseksou, Azzedine; Ruiz, Eliseo; Real, Jose A. (Wiley, 2016-08)

The highly stable nitrosyl iron(II) mononuclear complex [Fe(bztpen)(NO)](PF6)(2) (bztpen=N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethylenediamine) displays an S=1/2 <-> S=3/2 spin crossover (SCO) behavior (T-1/2=370 K, Delta ...

Now showing items 1-1 of 1