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[Fe(TPT)2/3{MI(CN)2}2]·nSolv (MI=Ag, Au): new bimetallic porous coordination polymers with spin-crossover properties

Arcis-Castillo, Zulema; Muñoz Roca, María del Carmen; Molnár, Gábor; Bousseksou, Azzedine; Real, José Antonio (Wiley-VCH Verlag, 2013-05-17)

Two new heterobimetallic porous coordination polymers with the formula [Fe(TPT)2/3{MI(CN)2}2]¿nSolv (TPT=[(2,4,6-tris(4-pyridyl)-1,3,5-triazine]; MI=Ag (nSolv=0, 1¿MeOH, 2¿CH2Cl2), Au (nSolv=0, 2¿CH2Cl2)) have been synthesized ...
Cyanido-Bridged FeII-MI Dimetallic Hofmann-Like Spin-Crossover Coordination Polymers Based on 2,6-Naphthyridine

Piñeiro-López, L.; Valverde-Muñoz, F. J.; Seredyuk, M.; Bartual-Murgui, C.; Muñoz Roca, María Del Carmen; Real, J. A. (John Wiley & Sons, 2018-01-31)

[EN] Two new 3D spin-crossover (SCO) Hofmann-type coordination polymers {Fe(2,6-naphthy)[Ag(CN)2][Ag2(CN)3]} (1; 2,6-naphthy = 2,6-naphthyridine) and {Fe(2,6-naphthy)- [Au(CN)2]2}·0.5PhNO2 (2) were synthesized and ...
Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex

Piñeiro López, Lucía; Ortega Villar, Norma; Muñoz Roca, María del Carmen; Molnar, Gabor; Cirera, Jordi; Moreno Esparza, Rafael; Ugalde Saldivar, Victor M.; Bousseksou, Azzedine; Ruiz, Eliseo; Real, Jose A. (Wiley, 2016-08)

The highly stable nitrosyl iron(II) mononuclear complex [Fe(bztpen)(NO)](PF6)(2) (bztpen=N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethylenediamine) displays an S=1/2 <-> S=3/2 spin crossover (SCO) behavior (T-1/2=370 K, Delta ...
Epitaxial Thin-Film vs Single Crystal Growth of 2D Hofmann-Type Iron(II) Materials: A Comparative Assessment of their Bi-Stable Spin Crossover Properties

Bartual-Murgui, Carlos; Rubio-Giménez, Victor; Meneses-Sánchez, Manuel; Valverde-Muñoz, Francisco Javier; Tatay, Sergio; Marti-Gastaldo, Carlos; Muñoz Roca, María del Carmen; Real, José Antonio (American Chemical Society, 2020-07)

[EN] Integration of the ON-OFF cooperative spin crossover (SCO) properties of FeII coordination polymers as components of electronic and/or spintronic devices is currently an area of great interest for potential applications. ...
Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal Organic Frameworks

Romero Morcillo, Tania; De la Pinta, Noelia; Callejo, Lorena M.; Piñeiro López, Lucía; Muñoz Roca, María del Carmen; Madariaga, Gotzon; Ferrer, Sacramento; Breczewski, Tomasz; Cortés, Roberto; Real, José A. (Wiley, 2015-08-17)

[Fe(tvp)(2)(NCS)(2)] (1) (tvp=trans-(4,4-vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two-dimensional grids. This uncommon supramolecular conformation defines square-sectional ...
Polymorphism and Pressure Driven Thermal Spin Crossover Phenomenon in [Fe(abpt)2(NCX)2] (X = S, and Se): Synthesis, Structure and Magnetic Properties

Gaspar, A. B.; Muñoz Roca, María Del Carmen; Moliner, N.; Ksenofontov, V.; Levchenko, G.; Gütlich, P.; Real, J. A. (Springer-Verlag, 2003-02)

[EN] The monomeric compounds [Fe(abpt)(2)(NCX)(2)] (X = S (1), Se (2) and abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) have been synthesized and characterized. They crystallize in the monoclinic P2(1)/n space group ...
Spin Crossover in Six-Coordinate [Fe(L)2(NCX)2] Compounds with L=DPQ=2,3-bis-(2'-pyridil)-quinoxaline, ABPT=4-amino-3,5-bis(pyridin-2-yl)-1,2,4-trazole and X=S, Se: synthesis, magnetic properties and single crystal studies

Moliner, N.; Muñoz Roca, María Del Carmen; Van Koningsbruggen, P.; Real, J. A. (Elsevier, 1998-06-01)

[EN] The iron(II) compounds of formulae [Fe(DPQ)2(NCS)2]·CO(CH)3)2(DPQ = 2,3-bis-(2¿-pyridyl)-quinoxaline) (1) and [Fe(ABPT)2-(NCX)2] (ABPT = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) X = S (2) and Se (3) were synthesized ...
Symmetry Breaking in Iron(II) Spin-Crossover Molecular Crystals

Ortega-Villar, Norma; Muñoz Roca, María del Carmen; Real, José A. (MDPI, 2016-03)

[EN] This review provides an up to date survey of a singular class of iron(II) spin crossover (SCO) molecular materials that undergo high-spin (HS) Ø low-spin (LS) phase transitions accompanied by crystallographic symmetry ...
Thermal-, Pressure- and Light-Induced Spin-Crossover Behaviour in the two-Dimensional Hofmann-Like Coordination Polymer [Fe(3-Clpy)2Pd(CN)4]

Martínez, Víctor; Arcís Castillo, Zulema; Muñoz Roca, María del Carmen; Gaspar, Ana B.; Etriard, C.; Letard, Jean-Francois; Terekhov, Sergey A.; Bukin, Gennadiy V.; Levchenko, Georgiy; Real, Jose A. (2013-02)

The thermal spin-crossover behaviour, photoexcitation and subsequent relaxation, as well as the pressure-induced spincrossover behaviour at 298 K are discussed for the non-porous two-dimensional Hofmann-like coordination ...
Thermal-,Pressure-, and Light-Induced Spin Transition in Novel Cyanide-Bridged FeII-AgI Bimetallic Compounds with Three-Dimensional Interpenetrating Double Structures {FeIILx[Ag(CN)2]2}·G

Niel, V.; Muñoz Roca, María Del Carmen; Gaspar, A. B.; Galet, A.; Levchenko, G.; Real, J. A. (John Wiley & Sons, 2002-05-17)

[EN] Low-spin, high-spin and spin-transition behaviours have been observed for the doubly interpenetrating three-dimensional bimetallic compounds {Fe-II(pz)[Ag(CN)(2)](2)}.pz (pz= pyrazine), {Fe-II(4,4'-bipy)(2)[Ag(CN)(2)](2)} ...

Now showing items 1-10 of 10

Browsing by Subject "Spin crossover"

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Browsing by Subject "Spin crossover"