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Synergy Between Spin Crossover and Metallophilicity in Triple Interpenetrated 3D Nets with the NbO Structure Type

Cerrado

Archivos

Galet;Niel;Muñoz - Synergy Between Spin Crossover and Metallophilicity in Triple Interpenetrated ....pdfVersión editorial (128.98 KB)

Fecha

2003-11-26

Autores

Galet, A.
Niel, V.
Real, J. A.

Directores

Unidades organizativas

...

Handle

https://riunet.upv.es/handle/10251/140877

Cita bibliográfica

Galet, A.; Niel, V.; Muñoz Roca, MDC.; Real, JA. (2003). Synergy Between Spin Crossover and Metallophilicity in Triple Interpenetrated 3D Nets with the NbO Structure Type. Journal of the American Chemical Society. 125(47):14224-14225. https://doi.org/10.1021/ja0377347

Titulación

Resumen

[EN] Self-assembly of [Ag(CN)2]-, 3-cyanopyridine, and iron(II) gives triple interpenetration of three-dimensional spin crossover (SCO) networks with the NbO topology, which interact each other via argentophilic interactions. Superposition of the networks along the c-axis defines an infinite mosaic of trigonal and hexagonal cross-sectional tubes where water molecules are installed. The structural changes associated with the SCO tune the homoatomic interactions and induce an uncommon change of the lattice volume.

Palabras clave

Iron, Quantum mechanics, Gold, Hysteresis, Materials

ISSN

0002-7863

ISBN

Fuente

Journal of the American Chemical Society

DOI

10.1021/ja0377347

Enlaces relacionados

https://doi.org/10.1021/ja0377347

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