Simancas Coloma, R.; Dari, D.; Velamazan, N.; Navarro Villalba, MT.; Cantin Sanz, A.; Jorda Moret, JL.; Sastre Navarro, GI.... (2010). Modular organic structure-directing agents for the synthesis of zeolites. Science. 330(6008):1219-1222. https://doi.org/10.1126/science.1196240
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/105370
Title:
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Modular organic structure-directing agents for the synthesis of zeolites
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Author:
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Simancas Coloma, Raquel
Dari, Djamal
Velamazan, Noemi
Navarro Villalba, Mª Teresa
Cantin Sanz, Angel
Jorda Moret, Jose Luis
Sastre Navarro, German Ignacio
Corma Canós, Avelino
Rey Garcia, Fernando
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UPV Unit:
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Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
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Issued date:
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Abstract:
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[EN] Organic structure-directing agents (OSDAs) are used to guide the formation of particular types of pores and channels during the synthesis of zeolites. We report that the use of highly versatile OSDAs based on phosphazenes ...[+]
[EN] Organic structure-directing agents (OSDAs) are used to guide the formation of particular types of pores and channels during the synthesis of zeolites. We report that the use of highly versatile OSDAs based on phosphazenes has been successfully introduced for the synthesis of zeolites. This approach has made possible the synthesis of the elusive boggsite zeolite, which is formed by 10- and 12-ring intersecting channels. This topology and these pore dimensions present interesting opportunities for catalysis in reactions of industrial relevance.
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Copyrigths:
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Cerrado |
Source:
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Science. (issn:
0036-8075
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DOI:
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10.1126/science.1196240
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Publisher:
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American Association for the Advancement of Science (AAAS)
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Publisher version:
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http://doi.org/10.1126/science.1196240
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Project ID:
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info:eu-repo/grantAgreement/MICINN//MAT2009-14528-C02-01/ES/Sintesis, Caracterizacion Avanzada Y Empleo En Procesos Industriales De Nuevas Zeolitas Obtenidos Con Cationes Organicos No Convencionales Como Agentes Directores De Estructura/
info:eu-repo/grantAgreement/MICINN//PLE2009-0054/ES/Nuevas Zeolitas para Procesos de Separación de Gases y Producción Sostenible de Productos Químicos/
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Thanks:
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The authors thank the Spanish government (projects MAT2009-14528-C02-01, PLE2009-0054, and CONSOLIDER INGENIO 2010) and Generalitat Valenciana (Project Prometeo) for financial support. R. S. and N.V. thank UPV and CSIC for ...[+]
The authors thank the Spanish government (projects MAT2009-14528-C02-01, PLE2009-0054, and CONSOLIDER INGENIO 2010) and Generalitat Valenciana (Project Prometeo) for financial support. R. S. and N.V. thank UPV and CSIC for Programa de Formacion de Personal Investigador and Junta para la Ampliacion de Estudios predoctoral fellowships, respectively. Further details on the crystal structure may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany [fax: (+49) 7247-808-666; e-mail: crysdata@fiz-Karlruhe.de], on quoting the depository number CDS-422193.
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Type:
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Artículo
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