Pozo, CD.; Corma Canós, A.; Iglesias, M.; Sánchez Alonso, F. (2012). Multisite solid (NHC) NN-Ru-catalysts for cascade reactions: Synthesis of secondary amines from nitro compounds. Journal of Catalysis. 291:110-116. https://doi.org/10.1016/j.jcat.2012.04.015
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/105408
Title:
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Multisite solid (NHC) NN-Ru-catalysts for cascade reactions: Synthesis of secondary amines from nitro compounds
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Author:
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Pozo, Carolina del
Corma Canós, Avelino
Iglesias, Marta
Sánchez Alonso, Felix
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UPV Unit:
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Universitat Politècnica de València. Departamento de Química - Departament de Química
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Issued date:
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Abstract:
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[EN] Supported ruthenium complexes based on electron-rich (NHC)NN-pincer-type ligands selectively catalyze the formation of substituted amines from nitroaromatics and carbonyl compounds through a series of consecutive steps ...[+]
[EN] Supported ruthenium complexes based on electron-rich (NHC)NN-pincer-type ligands selectively catalyze the formation of substituted amines from nitroaromatics and carbonyl compounds through a series of consecutive steps which involves the reduction of nitro group to amine, the formation of an imine or iminium ion intermediate, followed by in situ reduction to an alkylated amine of higher order in a single operation. Solid complexes result active and recyclable catalysts and no deactivation was observed after repeated recycling. (C) 2012 Elsevier Inc. All rights reserved.
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Subjects:
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MCM-41
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One-pot
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Domino
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Ruthenium
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NHC pincer ligand
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Supported catalysts
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Catalyst recycling
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Copyrigths:
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Cerrado |
Source:
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Journal of Catalysis. (issn:
0021-9517
)
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DOI:
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10.1016/j.jcat.2012.04.015
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Publisher:
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Elsevier
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Publisher version:
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http://dx.doi.org/10.1016/j.jcat.2012.04.015
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Project ID:
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info:eu-repo/grantAgreement/MICINN//MAT2011-29020-C02-01/ES/CATALIZADORES HIBRIDOS MULTIFUNCIONALES BASADOS EN UNIDADES ESTRUCTURALES ORGANICAS-INORGANICAS UTILIZADOS EN REACCIONES CASCADA/
info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/
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Thanks:
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We thank the Dirección General de Investigación Científica y Técnica of Spain (Projects MAT2011-29020-C02-02, Consolider Ingenio 2010-(CSD-0050-MULTICAT) for financial support.
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Type:
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Artículo
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