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dc.contributor.author | Dhakshinamoorthy, Amarajothi | es_ES |
dc.contributor.author | Alvaro Rodríguez, Maria Mercedes | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.date.accessioned | 2018-09-10T09:16:38Z | |
dc.date.available | 2018-09-10T09:16:38Z | |
dc.date.issued | 2012 | es_ES |
dc.identifier.issn | 0021-9517 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/106854 | |
dc.description.abstract | [EN] Iron metal organic framework [Fe(BTC)) loaded with N-hydroxyphthalimide (NHPI) promotes the aerobic oxidation of (cyclo)alkenes to give variable percentages of allylic oxidation products and the corresponding epoxide, dependidng on the nature of the substrate. In the case of cyclopentene and cyclohexene, aerobic oxidation catalyzed by NHPI/Fe(BTC) renders their corresponding unsaturated cyclic alcohol and ketone with 97% selectivity in 5 h at 6% and 12% conversion, respectively. Under the same experimental conditions, cyclooctene exhibited 95% selectivity toward the formation of cyclooctene oxide with 2% of cyclooctenol/one at 4 h. Cycloheptene as susbstrate exhibits an intermediate behavior, and the aerobic oxidation catalyzed by NHPI/Fe(BTC) leads to the formation of cycloheptenol/cycloheptenone with 77% selectivity, accompanied by 23% of cycloheptene oxide at 4 h. Further experiments with non-symmetric olefins exhibited also a mixture of products including epoxides and allyic products. A mechanism to explain these experimental results has been proposed. (C) 2012 Elsevier Inc. All rights reserved. | es_ES |
dc.description.sponsorship | Financial support by the Spanish DGI (CTQ-2010-18671 and CTQ2007-67805) and European Commission Integrated Project (MACADEMIA) is gratefully acknowledged. | |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Journal of Catalysis | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Aerobic oxidation | es_ES |
dc.subject | Epoxidation of cycloalkenes | es_ES |
dc.subject | Metal organic frameworks as solid | es_ES |
dc.subject | Catalysts | es_ES |
dc.subject | N-hydroxyphthalimide | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Aerobic oxidation of cycloalkenes catalyzed by iron metal organic framework containing N-hydroxyphthalimide | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.jcat.2012.02.015 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2010-18671/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MEC//CTQ2007-67805/ES/APLICACION DE NUEVOS DERIVADOS DEL PPV ENCAPSULADOS EN MATRICES DE SILICE EN LA PREPARACION DE TRANSISTORES DE CAMPO ELECTRICO Y RECTIFICADORES A ESCALA MICROMETRICA/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Dhakshinamoorthy, A.; Alvaro Rodríguez, MM.; García Gómez, H. (2012). Aerobic oxidation of cycloalkenes catalyzed by iron metal organic framework containing N-hydroxyphthalimide. Journal of Catalysis. 289:259-265. https://doi.org/10.1016/j.jcat.2012.02.015 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1016/j.jcat.2012.02.015 | es_ES |
dc.description.upvformatpinicio | 259 | es_ES |
dc.description.upvformatpfin | 265 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 289 | es_ES |
dc.relation.pasarela | S\240441 | es_ES |
dc.contributor.funder | Ministerio de Educación, Cultura y Deporte | es_ES |
dc.contributor.funder | Ministerio de Economía, Industria y Competitividad | es_ES |
dc.contributor.funder | European Commission |