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dc.contributor.author | Ottenwaelder, X.![]() |
es_ES |
dc.contributor.author | Aukauloo, A.![]() |
es_ES |
dc.contributor.author | Journaux, Y.![]() |
es_ES |
dc.contributor.author | Carrasco, R.![]() |
es_ES |
dc.contributor.author | Cano, J.![]() |
es_ES |
dc.contributor.author | Cervera, B.![]() |
es_ES |
dc.contributor.author | Castro, I.![]() |
es_ES |
dc.contributor.author | Cureli, S.![]() |
es_ES |
dc.contributor.author | Muñoz Roca, María Del Carmen![]() |
es_ES |
dc.contributor.author | Roselló, A. L.![]() |
es_ES |
dc.contributor.author | Soto, B.![]() |
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dc.contributor.author | Ruiz-García, R.![]() |
es_ES |
dc.date.accessioned | 2020-03-16T14:46:53Z | |
dc.date.available | 2020-03-16T14:46:53Z | |
dc.date.issued | 2005 | es_ES |
dc.identifier.issn | 1477-9226 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/138964 | |
dc.description.abstract | [EN] A series of four-coordinate square-planar nickel(II) complexes of o-phenylenebis(N¿-methyloxamidate) (L1) and related o-phenylene(N¿-methyloxamidate)oxamate (L2) and o-phenylenebis(oxamate) (L3) tetradentate ligands have been synthesized and characterized structurally, spectroscopically and electrochemically. The parent nickel(II)¿L1 complex presents an intense MLCT band in the UV region (¿max = 357 nm) and a distinctive 1 s ¿ 4p CT satellite in the Ni K-edge XANES spectrum (E = 8339.2 eV). These features together with the short Ni¿N(amidate) bond lengths (1.85¿1.93 Å) as revealed by the analysis of the Ni K-edge EXAFS spectrum and confirmed by single-crystal X-ray diffraction are typical of square-planar low spin (S = 0) NiII ions. The dianionic nickel(II) complexes, [NiIILi]2¿ (i = 1¿3), experience two redox processes in acetonitrile at 25 °C. The first redox process, at moderately low potentials (E1 = 0.12¿0.52 V vs. SCE), is a reversible one-electron metal-centered oxidation to the corresponding monoanionic nickel(III) complexes, [NiIIILi]¿. The second redox process, at relatively high potentials (E2 = 0.86¿1.04 V vs. SCE), is a quasireversible to irreversible one-electron oxidation largely centered on the o-benzenediamidate fragment of the non-innocent ligand, yielding the corresponding neutral nickel(III) complexes with a o-benzosemiquinonediimine ¿-cation radical ligand, [NiIII(Li)¿+]. The singly and doubly oxidized species of the parent nickel(II)¿L1 complex have been prepared by chemical oxidation and characterized spectroscopically in acetonitrile at ¿40 °C. The stable singly oxidized nickel(III)¿L1 species presents an intense LMCT band in the NIR region (¿max = 910 nm) and a rhombic X-band EPR spectrum (g1 = 2.193, g2 = 2.080 and g3 = 2.006) characteristic of square-planar low spin (S = 1/2) NiIII ions. The unstable double oxidized nickel(III)¿L1 ¿-cation radical species exhibits a rather intense visible band (¿max = 645 nm) that is tentatively assigned as a MLCT transition from the NiIII-benzosemiquinone type ground state to the NiIV excited state. | es_ES |
dc.description.sponsorship | This work was supported by the Ministerio de Ciencia y Tecnología (MCYT) (Spain) through the Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica (I + D + I) (BQU2001 2928) and the Ramón y Cajal programs. Further support from the European Community through the Human Potential Program Access to research infrastructures (Project CC005 97) is also acknowledged. B. S. thanks the Universitat de Valencia for a grant through the Una Nau de Solidaritat program. We are specially thankful to Dr I. Fernandez (Universitat de València) and Dr F. Villain (Universite Pierre et Marie Curie) for their assistance with the NMR and X-ray absorption measurements, respectively, and to Dr R. Pratt and Prof. T. D. P. Stack (Stanford University) for providing the thianthrenyl salt and access to low-temperature UV/VIS/NIR equipment, respectively | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | The Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Dalton Transactions | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject.classification | FISICA APLICADA | es_ES |
dc.title | Synyhesis, structure, spectroscopy and redox chemistry of square-planar nickel(II) complexes with tetradentate o-phenylenedioxamidates and related ligands | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/B502478A | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC//CC005 97 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICYT//BQU2001-2928/ES/Msíntesis, Estructura y Propiedades Magnéticas de Compuestos con Interacción de Canje entre Centros Metálicos/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada | es_ES |
dc.description.bibliographicCitation | Ottenwaelder, X.; Aukauloo, A.; Journaux, Y.; Carrasco, R.; Cano, J.; Cervera, B.; Castro, I.... (2005). Synyhesis, structure, spectroscopy and redox chemistry of square-planar nickel(II) complexes with tetradentate o-phenylenedioxamidates and related ligands. Dalton Transactions. 15:2516-2525. https://doi.org/10.1039/B502478A | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1039/B502478A | es_ES |
dc.description.upvformatpinicio | 2516 | es_ES |
dc.description.upvformatpfin | 2525 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 15 | es_ES |
dc.relation.pasarela | S\230680 | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | Ministerio de Ciencia y Tecnología | es_ES |
dc.description.references | Nag, K., & Chakravorty, A. (1980). Monovalent, trivalent and tetravalent nickel. Coordination Chemistry Reviews, 33(2), 87-147. doi:10.1016/s0010-8545(00)80405-1 | es_ES |
dc.description.references | Mcauley, A., & Norman, P. R. (1985). Kinetic Aspects of Redox Reactions of Nickel(III) Complexes. Israel Journal of Chemistry, 25(2), 106-111. doi:10.1002/ijch.198500017 | es_ES |
dc.description.references | Fabbrizzi, L., Licchelli, M., Perotti, A., Poggi, A., & Soresi, S. (1985). Nickel(III) and Copper(III) Complexes with 13- and 14-membered Tetra-aza Macrocycles. Ring-size and Medium Effects on the MIII/MIIRedox Couple Potentials. Israel Journal of Chemistry, 25(2), 112-117. doi:10.1002/ijch.198500018 | es_ES |
dc.description.references | Cocolios, P., & Kadish, K. M. (1985). Characterization of Several Metalloporphyrins in Unusual Oxidation States. The Effect of Axial and Equatorial Ligands. Israel Journal of Chemistry, 25(2), 138-147. doi:10.1002/ijch.198500022 | es_ES |
dc.description.references | Lappin, A. G., & McAuley, A. (1988). The Redox Chemistry of Nickel. Advances in Inorganic Chemistry, 241-295. doi:10.1016/s0898-8838(08)60233-0 | es_ES |
dc.description.references | Walsh, C. T., & Orme-Johnson, W. H. (1987). Nickel enzymes. Biochemistry, 26(16), 4901-4906. doi:10.1021/bi00390a001 | es_ES |
dc.description.references | Volbeda, A., Charon, M.-H., Piras, C., Hatchikian, E. C., Frey, M., & Fontecilla-Camps, J. C. (1995). Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigas. Nature, 373(6515), 580-587. doi:10.1038/373580a0 | es_ES |
dc.description.references | Ermler, U. (1997). Crystal Structure of Methyl-Coenzyme M Reductase: The Key Enzyme of Biological Methane Formation. Science, 278(5342), 1457-1462. doi:10.1126/science.278.5342.1457 | es_ES |
dc.description.references | Lee, J.-W., Roe, J.-H., & Kang, S.-O. (2002). Nickel-containing superoxide dismutase. Superoxide Dismutase, 90-101. doi:10.1016/s0076-6879(02)49324-x | es_ES |
dc.description.references | Palenik, B., Brahamsha, B., Larimer, F. W., Land, M., Hauser, L., Chain, P., … Waterbury, J. (2003). The genome of a motile marine Synechococcus. Nature, 424(6952), 1037-1042. doi:10.1038/nature01943 | es_ES |
dc.description.references | Cheng, C.-C., Rokita, S. E., & Burrows, C. J. (1993). Nickel(III)-Promoted DNA Cleavage with Ambient Dioxygen. Angewandte Chemie International Edition in English, 32(2), 277-278. doi:10.1002/anie.199302771 | es_ES |
dc.description.references | Burrows, C. J., Muller, J. G., Poulter, G. T., Rokita, S. E., Liptay, G., Trautwein-Fritz, K., … Weinhold, E. G. (1996). Nickel-Catalyzed Oxidations: from Hydrocarbons to DNA. Acta Chemica Scandinavica, 50, 337-344. doi:10.3891/acta.chem.scand.50-0337 | es_ES |
dc.description.references | Muller, J. G., Hickerson, R. P., Perez, R. J., & Burrows, C. J. (1997). DNA Damage from Sulfite Autoxidation Catalyzed by a Nickel(II) Peptide. Journal of the American Chemical Society, 119(7), 1501-1506. doi:10.1021/ja963701y | es_ES |
dc.description.references | Koola, J. D., & Kochi, J. K. (1987). Nickel catalysis of olefin epoxidation. Inorganic Chemistry, 26(6), 908-916. doi:10.1021/ic00253a026 | es_ES |
dc.description.references | Kinneary, J. F., Albert, J. S., & Burrows, C. J. (1988). Mechanistic studies of alkene epoxidation catalyzed by nickel(II) cyclam complexes. Oxygen-18 labeling and substituent effects. Journal of the American Chemical Society, 110(18), 6124-6129. doi:10.1021/ja00226a029 | es_ES |
dc.description.references | Machida, R., Kimura, E., & Kushi, Y. (1986). Coordination of pentadentate macrocycles, doubly deprotonated 1,4,7,10,13-pentaazacyclohexadecane-14,16-dione to high-spin nickel(II) and low-spin nickel(III). X-ray study of a novel redox system. Inorganic Chemistry, 25(19), 3461-3466. doi:10.1021/ic00239a029 | es_ES |
dc.description.references | Chen, D., & Martell, A. E. (1990). Oxygen insertion in the nickel(II) complexes of dioxopentaaza macrocyclic ligands. Journal of the American Chemical Society, 112(25), 9411-9412. doi:10.1021/ja00181a063 | es_ES |
dc.description.references | Chen, D., Motekaitis, R. J., & Martell, A. E. (1991). Dioxygen adducts of nickel(II) and cobalt(II) dioxopentaazamacrocyclic complexes: kinetics, stabilities, and hydroxylation of the ligands in the nickel dioxygen complexes. Inorganic Chemistry, 30(6), 1396-1402. doi:10.1021/ic00006a043 | es_ES |
dc.description.references | Cammack, R. (1988). Nickel in Metalloproteins. Advances in Inorganic Chemistry, 297-333. doi:10.1016/s0898-8838(08)60234-2 | es_ES |
dc.description.references | Halcrow, M. A., & Christou, G. (1994). Biomimetic Chemistry of Nickel. Chemical Reviews, 94(8), 2421-2481. doi:10.1021/cr00032a008 | es_ES |
dc.description.references | Burrows, C. J., & Rokita, S. E. (1994). Recognition of Guanine Structure in Nucleic Acids by Nickel Complexes. Accounts of Chemical Research, 27(10), 295-301. doi:10.1021/ar00046a002 | es_ES |
dc.description.references | Long, E. C. (1999). Ni(II)·Xaa-Xaa-His Metallopeptide−DNA/RNA Interactions†. Accounts of Chemical Research, 32(10), 827-836. doi:10.1021/ar980072j | es_ES |
dc.description.references | Connick, P. A., & Macor, K. A. (1991). Spectroscopic and electrochemical characterization of nickel .beta.-oxoporphyrins: identification of nickel(III) oxidation products. Inorganic Chemistry, 30(24), 4654-4663. doi:10.1021/ic00024a038 | es_ES |
dc.description.references | Azevedo, F., Carrondo, M. A. A. F. d. C. T., de Castro, B., Convery, M., Domingues, D., Freire, C., … Santos, I. C. (1994). Electrochemical and structural studies of nickel(II) complexes with N2O2 Schiff base ligands 2. Crystal and molecular structure of N,N′-l,2-ethane-1,2-diyl-bis(2- hydroxyacetophenonylideneiminate)nickel(II), N, N′-1,2-cis cyclohexane-1,2-diyl-bis(2-hydroxyacetophenonylideneiminate)- nickel(II) and N,N′-1,2-benzene-1,2-diyl-bis(3,5-dichlorosalicylideneiminate)nickel(II). Inorganica Chimica Acta, 219(1-2), 43-54. doi:10.1016/0020-1693(94)03821-x | es_ES |
dc.description.references | Pereira, E., Gomes, L., & de Castro, B. (1998). Synthesis, spectroscopic and electrochemical study of nickel(II) complexes with tetradentate asymmetric Schiff bases derived from salicylaldehyde and methyl-2-amino-1-cyclopentenedithiocarboxylate. Inorganica Chimica Acta, 271(1-2), 83-92. doi:10.1016/s0020-1693(97)05904-5 | es_ES |
dc.description.references | Freire, C., & Castro, B. de. (1998). Spectroscopic characterisation of electrogenerated nickel(III) species. Complexes with N2O2 Schiff-base ligands derived from salicylaldehyde. Journal of the Chemical Society, Dalton Transactions, (9), 1491-1498. doi:10.1039/a708231b | es_ES |
dc.description.references | Kruger, H. J., Peng, G., & Holm, R. H. (1991). Low-potential nickel(III,II) complexes: new systems based on tetradentate amidate-thiolate ligands and the influence of ligand structure on potentials in relation to the nickel site in [NiFe]-hydrogenases. Inorganic Chemistry, 30(4), 734-742. doi:10.1021/ic00004a025 | es_ES |
dc.description.references | Hanss, J., & Krüger, H.-J. (1998). First Isolation and Structural Characterization of a Nickel(III) Complex Containing Aliphatic Thiolate Donors. Angewandte Chemie International Edition, 37(3), 360-363. doi:10.1002/(sici)1521-3773(19980216)37:3<360::aid-anie360>3.0.co;2-p | es_ES |
dc.description.references | Weeks, C. L., Turner, P., Fenton, R. R., & Lay, P. A. (2002). Nickel(ii) complexes with amide ligands: oxidative dehydrogenation of the amines in a tetradentate diamide–diamine ligand. Journal of the Chemical Society, Dalton Transactions, (6), 931. doi:10.1039/b107378h | es_ES |
dc.description.references | Kruger, H. J., & Holm, R. H. (1990). Stabilization of trivalent nickel in tetragonal NiS4N2 and NiN6 environments: synthesis, structures, redox potentials and observations related to [NiFe]-hydrogenases. Journal of the American Chemical Society, 112(8), 2955-2963. doi:10.1021/ja00164a018 | es_ES |
dc.description.references | Baidya, N., Olmstead, M. M., & Mascharak, P. K. (1992). Mononuclear nickel(II) complex with [NiN3S2] chromophore that readily affords the nickel(I) and nickel(III) analogs: probe into the redox behavior of the nickel site in [iron-nickel] hydrogenases. Journal of the American Chemical Society, 114(24), 9666-9668. doi:10.1021/ja00050a061 | es_ES |
dc.description.references | Marganian, C. A., Vazir, H., Baidya, N., Olmstead, M. M., & Mascharak, P. K. (1995). Toward Functional Models of the Nickel Sites in [FeNi] and [FeNiSe] Hydrogenases: Syntheses, Structures, and Reactivities of Nickel(II) Complexes Containing [NiN3S2] and [NiN3Se2] Chromophores. Journal of the American Chemical Society, 117(5), 1584-1594. doi:10.1021/ja00110a013 | es_ES |
dc.description.references | Patra, A. K., & Mukherjee, R. (1999). Bivalent, Trivalent, and Tetravalent Nickel Complexes with a Common Tridentate Deprotonated Pyridine Bis-Amide Ligand. Molecular Structures of Nickel(II) and Nickel(IV) and Redox Activity. Inorganic Chemistry, 38(7), 1388-1393. doi:10.1021/ic980672e | es_ES |
dc.description.references | De Bruin, B., Bill, E., Bothe, E., Weyhermüller, T., & Wieghardt, K. (2000). Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n(n= 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)†. Inorganic Chemistry, 39(13), 2936-2947. doi:10.1021/ic000113j | es_ES |
dc.description.references | Hikichi, S., Yoshizawa, M., Sasakura, Y., Akita, M., & Moro-oka, Y. (1998). First Synthesis and Structural Characterization of Dinuclear M(III) Bis(μ-oxo) Complexes of Nickel and Cobalt with Hydrotris(pyrazolyl)borate Ligand†. Journal of the American Chemical Society, 120(40), 10567-10568. doi:10.1021/ja981837l | es_ES |
dc.description.references | Itoh, S., Bandoh, H., Nagatomo, S., Kitagawa, T., & Fukuzumi, S. (1999). Aliphatic Hydroxylation by a Bis(μ-oxo)dinickel(III) Complex. Journal of the American Chemical Society, 121(38), 8945-8946. doi:10.1021/ja991326e | es_ES |
dc.description.references | Shiren, K., Ogo, S., Fujinami, S., Hayashi, H., Suzuki, M., Uehara, A., … Moro-oka, Y. (2000). Synthesis, Structures, and Properties of Bis(μ-oxo)nickel(III) and Bis(μ-superoxo)nickel(II) Complexes: An Unusual Conversion of a NiIII2(μ-O)2Core into a NiII2(μ-OO)2Core by H2O2and Oxygenation of Ligand. Journal of the American Chemical Society, 122(2), 254-262. doi:10.1021/ja990311d | es_ES |
dc.description.references | Bag, B., Mondal, N., Mitra, S., & Rosair, G. (2000). The first thermally-stable singly oxo-bridged dinuclear Ni(iii) complex. Chemical Communications, (18), 1729-1730. doi:10.1039/b004165n | es_ES |
dc.description.references | Bossu, F. P., & Margerum, D. W. (1976). The stabilization of trivalent nickel in deprotonated-peptide complexes. Journal of the American Chemical Society, 98(13), 4003-4004. doi:10.1021/ja00429a047 | es_ES |
dc.description.references | Bossu, F. P., & Margerum, D. W. (1977). Electrode potentials of nickel(III)- and nickel(II)-peptide complexes. Inorganic Chemistry, 16(5), 1210-1214. doi:10.1021/ic50171a047 | es_ES |
dc.description.references | Anson, F. C., Collins, T. J., Richmond, T. G., Santarsiero, B. D., Toth, J. E., & Treco, B. G. R. T. (1987). Highly stabilized copper(III) complexes. Journal of the American Chemical Society, 109(10), 2974-2979. doi:10.1021/ja00244a020 | es_ES |
dc.description.references | Steggerda, J. J., Bour, J. J., & Birker, P. J. M. W. L. (1971). Copper(III) and nickel(III) complexes of biuret and oxamide. Inorganic Chemistry, 10(6), 1202-1205. doi:10.1021/ic50100a021 | es_ES |
dc.description.references | Ruiz, R., Faus, J., Lloret, F., Julve, M., & Journaux, Y. (1999). Coordination chemistry of N,N′-bis(coordinating group substituted)oxamides: a rational design of nuclearity tailored polynuclear complexes. Coordination Chemistry Reviews, 193-195, 1069-1117. doi:10.1016/s0010-8545(99)00138-1 | es_ES |
dc.description.references | Ruiz, R., Surville-Barland, C., Aukauloo, A., Anxolabehere-Mallart, E., Journaux, Y., Cano, J., & Muñoz, M. C. (1997). Stabilization of copper(III) complexes by disubstituted oxamides and related ligands. Journal of the Chemical Society, Dalton Transactions, (5), 745-752. doi:10.1039/a607572j | es_ES |
dc.description.references | Cervera, B., Sanz, J. L., Ibáñez, M. J., Vila, G., LLoret, F., Julve, M., … Muñoz, M. C. (1998). Stabilization of copper(III) complexes by substituted oxamate ligands. Journal of the Chemical Society, Dalton Transactions, (5), 781-790. doi:10.1039/a706964b | es_ES |
dc.description.references | DuBois, J. L., Mukherjee, P., Stack, T. D. P., Hedman, B., Solomon, E. I., & Hodgson, K. O. (2000). A Systematic K-edge X-ray Absorption Spectroscopic Study of Cu(III) Sites. Journal of the American Chemical Society, 122(24), 5775-5787. doi:10.1021/ja993134p | es_ES |
dc.description.references | Fernández, I., Pedro, J., Rosello, A. L., Ruiz, R., Ottenwaelder, X., & Journaux, Y. (1998). Aerobic epoxidation of olefins catalysed by square-planar nickel(II) complexes of bis- N , N ′-disubstituted oxamides and related ligands. Tetrahedron Letters, 39(18), 2869-2872. doi:10.1016/s0040-4039(98)00321-9 | es_ES |
dc.description.references | Blay, G., Benach, E., Fernández, I., Galletero, S., Pedro, J. R., & Ruiz, R. (2000). Catalytic Aerobic Oxidative Cleavage of Oximes, Tosylhydrazones and N,N-Dimethylhydrazones to Carbonyl Compounds. Synthesis, 2000(03), 403-406. doi:10.1055/s-2000-6347 | es_ES |
dc.description.references | Kosugi, N., Yokoyama, T., Asakura, K., & Kuroda, H. (1984). Polarized Cu K-edge XANES of square planar CuCl42− ion. Experimental and theoretical evidence for shake-down phenomena. Chemical Physics, 91(2), 249-256. doi:10.1016/0301-0104(84)80058-0 | es_ES |
dc.description.references | Bair, R. A., & Goddard, W. A. (1980). Ab initiostudies of the x-ray absorption edge in copper complexes. I. AtomicCu2+and Cu(ii)Cl2. Physical Review B, 22(6), 2767-2776. doi:10.1103/physrevb.22.2767 | es_ES |
dc.description.references | Shadle, S. E., Penner-Hahn, J. E., Schugar, H. J., Hedman, B., Hodgson, K. O., & Solomon, E. I. (1993). X-ray absorption spectroscopic studies of the blue copper site: metal and ligand K-edge studies to probe the origin of the EPR hyperfine splitting in plastocyanin. Journal of the American Chemical Society, 115(2), 767-776. doi:10.1021/ja00055a057 | es_ES |
dc.description.references | Hahn, J. E., Scott, R. A., Hodgson, K. O., Doniach, S., Desjardins, S. R., & Solomon, E. I. (1982). Observation of an electric quadrupole transition in the X-ray absorption spectrum of a Cu(II) complex. Chemical Physics Letters, 88(6), 595-598. doi:10.1016/0009-2614(82)85016-1 | es_ES |
dc.description.references | Roux, C., Zarembowitch, J., Itie, J. P., Verdaguer, M., Dartyge, E., Fontaine, A., & Tolentino, H. (1991). Pressure-induced spin-state crossovers in six-coordinate cobalt(II) complexes: a near-edge x-ray absorption study. Inorganic Chemistry, 30(16), 3174-3179. doi:10.1021/ic00016a014 | es_ES |
dc.description.references | Colpas, G. J., Maroney, M. J., Bagyinka, C., Kumar, M., Willis, W. S., Suib, S. L., … Baidya, N. (1991). X-ray spectroscopic studies of nickel complexes, with application to the structure of nickel sites in hydrogenases. Inorganic Chemistry, 30(5), 920-928. doi:10.1021/ic00005a010 | es_ES |
dc.description.references | Fabretti, A. C., Giusti, A., Albano, V. G., Castellari, C., Gatteschi, D., & Sessoli, R. (1991). Synthesis, molecular structure, and magnetic properties of [CuLNi(H2O)2LCu][ClO4]2·4H2O [H2L =N,N′-bis(3-amino-2,2-dimethylpropyl)oxamide] and its trinickel homologue. J. Chem. Soc., Dalton Trans., (8), 2133-2137. doi:10.1039/dt9910002133 | es_ES |
dc.description.references | Ning Chen, Z., Xia Tang, W., Chen, J., Zheng, P. J., Chen, C. G., & Yu, K. B. (1994). Synthesis, crystal structure and magnetic properties of dinuclear nickel(II) complexes bridged by oxamides. Polyhedron, 13(6-7), 873-879. doi:10.1016/s0277-5387(00)83003-x | es_ES |
dc.description.references | Ruiz, R., Surville-Barland, C., Journaux, Y., Colin, J. C., Castro, I., Cervera, B., … Sapiña, F. (1997). A Family of Oxamido-Bridged MnIICuIIBimetallic Molecular-Based Ferrimagnets: Synthesis, EXAFS Structural Characterization, and Magnetic Properties. Chemistry of Materials, 9(1), 201-209. doi:10.1021/cm9602961 | es_ES |
dc.description.references | Surville-Barland, C., Ruiz, R., Aukauloo, A., Journaux, Y., Castro, I., Cervera, B., … Sapin˜a, F. (1998). Tuning up the Tc in Mn(II)Cu(II) bimetallic planes and design of molecular-based magnets. Inorganica Chimica Acta, 278(2), 159-169. doi:10.1016/s0020-1693(98)00016-4 | es_ES |
dc.description.references | Collins, T. J. (1994). Designing Ligands for Oxidizing Complexes. Accounts of Chemical Research, 27(9), 279-285. doi:10.1021/ar00045a004 | es_ES |
dc.description.references | Mederos, A., Domı́nguez, S., Hernández-Molina, R., Sanchiz, J., & Brito, F. (1999). Coordinating ability of phenylenediamines. Coordination Chemistry Reviews, 193-195, 913-939. doi:10.1016/s0010-8545(99)00084-3 | es_ES |
dc.description.references | Kadish, K. M., & Morrison, M. M. (1976). Substituent effects on the oxidation-reduction reactions of nickel para-substituted tetraphenylporphyrin in nonaqueous media. Inorganic Chemistry, 15(4), 980-982. doi:10.1021/ic50158a055 | es_ES |
dc.description.references | Connelly, N. G., & Geiger, W. E. (1996). Chemical Redox Agents for Organometallic Chemistry. Chemical Reviews, 96(2), 877-910. doi:10.1021/cr940053x | es_ES |
dc.description.references | Lee, W. K., Liu, B., Park, C. W., Shine, H. J., & Whitmire, K. H. (1999). Addition of Thianthrene Cation Radical to Cycloalkenes. An Unexpected Monoadduct. The Journal of Organic Chemistry, 64(25), 9206-9210. doi:10.1021/jo9911241 | es_ES |
dc.description.references | Villain, F., Briois, V., Castro, I., Helary, C., & Verdaguer, M. (1993). Multipurpose x-ray absorption cell. Analytical Chemistry, 65(18), 2545-2548. doi:10.1021/ac00066a026 | es_ES |