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Free ion diffusivity and charge concentration on cross-linked Polymeric Ionic Liquid iongels films based on sulfonated zwitterion salts and Lithium ions

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Free ion diffusivity and charge concentration on cross-linked Polymeric Ionic Liquid iongels films based on sulfonated zwitterion salts and Lithium ions

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dc.contributor.author Valverde, D. es_ES
dc.contributor.author Garcia Bernabe, Abel es_ES
dc.contributor.author Andrio Balado, Andreu es_ES
dc.contributor.author Garcia-Verdugo, Eduardo es_ES
dc.contributor.author Luis Lafuente, Santiago es_ES
dc.contributor.author Compañ Moreno, Vicente es_ES
dc.date.accessioned 2020-04-17T12:50:31Z
dc.date.available 2020-04-17T12:50:31Z
dc.date.issued 2019-08-28 es_ES
dc.identifier.issn 1463-9076 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140918
dc.description.abstract [EN] The properties of various mixtures of a zwitterionic ionic liquid (ZIs-1) and LiNTf 2, including their conductivity, have been studied showing how they can be adjusted through their molar composition. Conductivity tends to increase with the LiNTf2 content although it presents a minimum at the region close to the eutectic point. These mixtures also provide excellent features as liquid phases for the preparation of composite materials based on crosslinked PILs. The prepared films display excellent and tuneable properties as conducting materials, with conductivities that can be higher than 10 2 S cm 1 above 100 1C. The selected polymeric compositions show very good mechanical properties and thermal stability, even for low crosslinking degrees, along with a suitable flexibility and good transparency. The final properties of the films correlate with the composition of the monomeric mixture used and with that of the ZIs-1:LiNTf2 mixture. es_ES
dc.description.sponsorship Financial support has been provided by MINECO (ENE/2015-69203-R and RTI2018-098233-B-C22) and Generalitat Valenciana (PROMETEO/2016/071). Technical support from the SECIC of the UJI is also acknowledged. DV thanks UNED (Costa Rica) for a predoctoral fellowship. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Physical Chemistry Chemical Physics es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Free ion diffusivity and charge concentration on cross-linked Polymeric Ionic Liquid iongels films based on sulfonated zwitterion salts and Lithium ions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c9cp01903k es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098233-B-C22/ES/NUEVOS PROCESOS MULTI-CATALITICOS VERDES BASADOS EN LA TECNOLOGIA DE LOS LIQUIDOS IONICOS: DESDE LAS MATERIAS PRIMAS SENCILLAS HASTA LOS QUIMICOS CON VALOR AÑADIDO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2016%2F071/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//ENE2015-69203-R/ES/DESARROLLO Y EVALUACION DE NUEVAS MEMBRANAS POLIMERICAS REFORZADAS CON NANOFIBRAS PARA SU APLICACION EN PILAS DE COMBUSTIBLE CON ELEVADA ESTABILIDAD TERMICA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation Valverde, D.; Garcia Bernabe, A.; Andrio Balado, A.; Garcia-Verdugo, E.; Luis Lafuente, S.; Compañ Moreno, V. (2019). Free ion diffusivity and charge concentration on cross-linked Polymeric Ionic Liquid iongels films based on sulfonated zwitterion salts and Lithium ions. Physical Chemistry Chemical Physics. 21(32):17923-17932. https://doi.org/10.1039/c9cp01903k es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c9cp01903k es_ES
dc.description.upvformatpinicio 17923 es_ES
dc.description.upvformatpfin 17932 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 21 es_ES
dc.description.issue 32 es_ES
dc.relation.pasarela S\396542 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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