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CuO improved (Sn,Sb)O2 ceramic anodes for electrochemical advanced oxidation processes

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CuO improved (Sn,Sb)O2 ceramic anodes for electrochemical advanced oxidation processes

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dc.contributor.author Sánchez-Rivera, M.J. es_ES
dc.contributor.author Giner-Sanz, Juan José es_ES
dc.contributor.author Pérez-Herranz, Valentín es_ES
dc.contributor.author Mestre, S. es_ES
dc.date.accessioned 2020-04-30T06:21:16Z
dc.date.available 2020-04-30T06:21:16Z
dc.date.issued 2019-04-02 es_ES
dc.identifier.issn 1546-542X es_ES
dc.identifier.uri http://hdl.handle.net/10251/142040
dc.description.abstract [EN] Antimony¿doped tin oxide electrodes with CuO as sintering aid are presented as an economical alternative to metal¿based electrodes, intended for the electrooxidation process of emerging and recalcitrant organic contaminants in wastewaters. The CuO proportion has been optimized to obtain densified electrodes with a mild thermal cycle (Tmax = 1200°C). One of the manufactured electrodes (97.8 mol.% of SnO2, 1.0 mol.% of Sb2O3, and 1.2 mol.% of CuO) was selected for electrochemical characterization from a physical and morphological analysis. The electrochemical behavior of the selected electrode showed that the addition of CuO as sintering aid widens the electrochemical window and increases the electrode ¿inactivity¿, with respect to an (Sn, Sb)O2 electrode synthesized in the same conditions. In return, the (Sn,Sb,Cu)O2 electrode presents a significantly lower electrochemical rugosity factor. Moreover, the addition of CuO does not change the oxygen evolution reaction mechanism, but it modifies the kinetic parameters, leading to a larger accumulation of hydroxyl radicals. Consequently, the addition of CuO as sintering aid significantly improves the electrochemical properties of the electrode as an electrochemical advanced oxidation process anode with respect to the (Sn,Sb)O2 electrode, at the expense of worsening its electrochemical roughness factor. The results of the electrochemical characterization were confirmed by Norfloxacin degradation tests. es_ES
dc.description.sponsorship The authors are very grateful to the Ministerio de Economia y Competitividad (Projects: CTQ2015-65202-C2-1-R and CTQ2015-65202-C2-2-R) and to the European Regional Development Fund (FEDER), for their economic support. es_ES
dc.language Inglés es_ES
dc.publisher Blackwell Publishing es_ES
dc.relation.ispartof International Journal of Applied Ceramic Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Electrical conductivity es_ES
dc.subject Electrodes es_ES
dc.subject Oxidation process es_ES
dc.subject Sintering es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.subject.classification INGENIERIA NUCLEAR es_ES
dc.title CuO improved (Sn,Sb)O2 ceramic anodes for electrochemical advanced oxidation processes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1111/ijac.13149 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-65202-C2-2-R/ES/NUEVOS ELECTRODOS CERAMICOS MEJORADOS MEDIANTE NANOTECNOLOGIA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-65202-C2-1-R/ES/CARACTERIZACION ELECTROQUIMICA DE ELECTRODOS CERAMICOS Y APLICACION A PROCESOS ELECTROQUIMICOS DE OXIDACION AVANZADA/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Sánchez-Rivera, M.; Giner-Sanz, JJ.; Pérez-Herranz, V.; Mestre, S. (2019). CuO improved (Sn,Sb)O2 ceramic anodes for electrochemical advanced oxidation processes. International Journal of Applied Ceramic Technology. 16(3):1274-1285. https://doi.org/10.1111/ijac.13149 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1111/ijac.13149 es_ES
dc.description.upvformatpinicio 1274 es_ES
dc.description.upvformatpfin 1285 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 16 es_ES
dc.description.issue 3 es_ES
dc.relation.pasarela S\390441 es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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