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dc.contributor.author | Vanti, L. | es_ES |
dc.contributor.author | Alauddin, S. Mohd | es_ES |
dc.contributor.author | Zaton, D. | es_ES |
dc.contributor.author | Aripin, N.F.K. | es_ES |
dc.contributor.author | Giaccinti-Baschetti, M. | es_ES |
dc.contributor.author | Imrie, C.T. | es_ES |
dc.contributor.author | Ribes-Greus, A. | es_ES |
dc.contributor.author | Martinez-Felipe, A. | es_ES |
dc.date.accessioned | 2020-06-12T03:34:06Z | |
dc.date.available | 2020-06-12T03:34:06Z | |
dc.date.issued | 2018-12 | es_ES |
dc.identifier.issn | 0014-3057 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/146185 | |
dc.description.abstract | [EN] We have prepared a series of new ionically conducting polymer electrolytes consisting of side-chain liquid crystal terpolymers with mesogenic azobenzenes, sulfonic acid groups and methyl methacrylate. The poly[10-(4-methoxyazobenzene -4'-oxy)decyl methacrylate] -co-poly[2-acrylamido-2-methyl-1-propanesulfonic acid]-copoly [methyl methacrylate]s, 10-MeOAzB/AMPS/MMA terpolymers, were synthesised by a one-pot conventional radical polymerisation. All samples were characterised by NMR, GPC/SEC, FT-IR, POM, XRD, DSC, UV-visible spectrophotometry and EIS. The terpolymers have light responsive properties, and exhibit liquid crystallinity over a wide range of compositions. Above a certain threshold of AMPS content, the 10-MeOAzB/AMPS/MMA terpolymers exhibit ionic conductivities in the 10(-8)-10(-4)S.cm(-1) range, with signs of decoupling of ionic mobility from segmental motions of the polymer. | es_ES |
dc.description.sponsorship | ARG and AMF thank the financial support of the Generalitat Valenciana, through the Grisolia and Forteza programs, and the Spanish Ministry of Science and Innovation, through the Research Projects ENE2007-67584-C03 and UPOVCE-3E-013 and the awarding of two FPI and FPU pre-doctoral grants. AMF and NFKA would like to thank the Royal Academy of Engineering for the award of the Newton Research Collaboration Programme grant NRCP1516/4/61. AMF acknowledges the School of Engineering of the University of Aberdeen for financial support. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | European Polymer Journal | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Side-chain liquid crystal polymers | es_ES |
dc.subject | Polymer electrolytes | es_ES |
dc.subject | Light responsive materials | es_ES |
dc.subject.classification | MAQUINAS Y MOTORES TERMICOS | es_ES |
dc.title | Ionically conducting and photoresponsive liquid crystalline terpolymers: Towards multifunctional polymer electrolytes | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.eurpolymj.2018.08.033 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//UPOV08-3E-013/ES/ADQUISICIÓN DE EQUIPO PARA MEDIDAS DIELÉCTRICAS Y DE POLARIZACIÓN PARA NUEVOS MATERIALES APLICADOS A TECNOLOGÍAS ENERGÉTICAS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/Royal Academy of Engineering//NRCP1516%2F4%2F61/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MEC//ENE2007-67584-C03-02/ES/ESTUDIO DE PILAS DE COMBUSTIBLE DISEÑADAS CON MEMBRANAS POLIMERICAS DOTADAS DE CONTROL MORFOLOGICO PARA BIO-ALCOHOLES/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//ENE2014-53734-C2-1-R/ES/DISEÑO Y VALIDACION DE MEMBRANAS CON CONTROL MORFOLOGICO PARA SU USO EN PILAS DE COMBUSTIBLE DE BAJA TEMPERATURA SOSTENIBLES EN VEHICULOS EFICIENTES NO TRIPULADOS/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Máquinas y Motores Térmicos - Departament de Màquines i Motors Tèrmics | es_ES |
dc.description.bibliographicCitation | Vanti, L.; Alauddin, SM.; Zaton, D.; Aripin, N.; Giaccinti-Baschetti, M.; Imrie, C.; Ribes-Greus, A.... (2018). Ionically conducting and photoresponsive liquid crystalline terpolymers: Towards multifunctional polymer electrolytes. European Polymer Journal. 109:124-132. https://doi.org/10.1016/j.eurpolymj.2018.08.033 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1016/j.eurpolymj.2018.08.033 | es_ES |
dc.description.upvformatpinicio | 124 | es_ES |
dc.description.upvformatpfin | 132 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 109 | es_ES |
dc.relation.pasarela | S\379084 | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | University of Aberdeen | es_ES |
dc.contributor.funder | Ministerio de Economía y Empresa | es_ES |
dc.contributor.funder | Royal Academy of Engineering, Reino Unido | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | Ministerio de Educación y Ciencia | es_ES |