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Ionically conducting and photoresponsive liquid crystalline terpolymers: Towards multifunctional polymer electrolytes

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Ionically conducting and photoresponsive liquid crystalline terpolymers: Towards multifunctional polymer electrolytes

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dc.contributor.author Vanti, L. es_ES
dc.contributor.author Alauddin, S. Mohd es_ES
dc.contributor.author Zaton, D. es_ES
dc.contributor.author Aripin, N.F.K. es_ES
dc.contributor.author Giaccinti-Baschetti, M. es_ES
dc.contributor.author Imrie, C.T. es_ES
dc.contributor.author Ribes-Greus, A. es_ES
dc.contributor.author Martinez-Felipe, A. es_ES
dc.date.accessioned 2020-06-12T03:34:06Z
dc.date.available 2020-06-12T03:34:06Z
dc.date.issued 2018-12 es_ES
dc.identifier.issn 0014-3057 es_ES
dc.identifier.uri http://hdl.handle.net/10251/146185
dc.description.abstract [EN] We have prepared a series of new ionically conducting polymer electrolytes consisting of side-chain liquid crystal terpolymers with mesogenic azobenzenes, sulfonic acid groups and methyl methacrylate. The poly[10-(4-methoxyazobenzene -4'-oxy)decyl methacrylate] -co-poly[2-acrylamido-2-methyl-1-propanesulfonic acid]-copoly [methyl methacrylate]s, 10-MeOAzB/AMPS/MMA terpolymers, were synthesised by a one-pot conventional radical polymerisation. All samples were characterised by NMR, GPC/SEC, FT-IR, POM, XRD, DSC, UV-visible spectrophotometry and EIS. The terpolymers have light responsive properties, and exhibit liquid crystallinity over a wide range of compositions. Above a certain threshold of AMPS content, the 10-MeOAzB/AMPS/MMA terpolymers exhibit ionic conductivities in the 10(-8)-10(-4)S.cm(-1) range, with signs of decoupling of ionic mobility from segmental motions of the polymer. es_ES
dc.description.sponsorship ARG and AMF thank the financial support of the Generalitat Valenciana, through the Grisolia and Forteza programs, and the Spanish Ministry of Science and Innovation, through the Research Projects ENE2007-67584-C03 and UPOVCE-3E-013 and the awarding of two FPI and FPU pre-doctoral grants. AMF and NFKA would like to thank the Royal Academy of Engineering for the award of the Newton Research Collaboration Programme grant NRCP1516/4/61. AMF acknowledges the School of Engineering of the University of Aberdeen for financial support. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation MICINN/UPOVCE-3E-013 es_ES
dc.relation Royal Academy of Engineering, UK/NRCP1516/4/61 es_ES
dc.relation MINISTERIO DE EDUCACION /ENE2007-67584-C03-02 es_ES
dc.relation MINECO/ENE2014-53734-C2-1-R-AR es_ES
dc.relation.ispartof European Polymer Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Side-chain liquid crystal polymers es_ES
dc.subject Polymer electrolytes es_ES
dc.subject Light responsive materials es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Ionically conducting and photoresponsive liquid crystalline terpolymers: Towards multifunctional polymer electrolytes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.eurpolymj.2018.08.033 es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Máquinas y Motores Térmicos - Departament de Màquines i Motors Tèrmics es_ES
dc.description.bibliographicCitation Vanti, L.; Alauddin, SM.; Zaton, D.; Aripin, N.; Giaccinti-Baschetti, M.; Imrie, C.; Ribes-Greus, A.... (2018). Ionically conducting and photoresponsive liquid crystalline terpolymers: Towards multifunctional polymer electrolytes. European Polymer Journal. 109:124-132. https://doi.org/10.1016/j.eurpolymj.2018.08.033 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.eurpolymj.2018.08.033 es_ES
dc.description.upvformatpinicio 124 es_ES
dc.description.upvformatpfin 132 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 109 es_ES
dc.relation.pasarela S\379084 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder University of Aberdeen es_ES
dc.contributor.funder Ministerio de Educación es_ES
dc.contributor.funder Ministerio de Economía y Empresa es_ES
dc.contributor.funder Royal Academy of Engineering, UK es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES


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