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Glass wool: a novel support for heterogeneous catalysis

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Glass wool: a novel support for heterogeneous catalysis

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dc.contributor.author Elhage, Ayda es_ES
dc.contributor.author Wang, Bowen es_ES
dc.contributor.author Marina, Nancy es_ES
dc.contributor.author Marín García, Mª Luisa es_ES
dc.contributor.author Cruz, Menandro es_ES
dc.contributor.author Lanterna, Anabel E. es_ES
dc.contributor.author Scaiano, Juan C. es_ES
dc.date.accessioned 2020-06-24T03:31:30Z
dc.date.available 2020-06-24T03:31:30Z
dc.date.issued 2018-09-07 es_ES
dc.identifier.issn 2041-6520 es_ES
dc.identifier.uri http://hdl.handle.net/10251/146879
dc.description.abstract [EN] Heterogeneous catalysis presents significant advantages over homogeneous catalysis such as ease of separation and reuse of the catalyst. Here we show that a very inexpensive, manageable and widely available material - glass wool - can act as a catalyst support for a number of different reactions. Different metal and metal oxide nanoparticles, based on Pd, Co, Cu, Au and Ru, were deposited on glass wool and used as heterogeneous catalysts for a variety of thermal and photochemical organic reactions including reductive de-halogenation of aryl halides, reduction of nitrobenzene, Csp(3)-Csp(3) couplings, N-C heterocycloadditions (click chemistry) and Csp-Csp(2) couplings (Sonogashira couplings). The use of glass wool as a catalyst support for important organic reactions, particularly C-C couplings, opens the opportunity to develop economical heterogeneous catalysts with excellent potential for flow photo-chemistry application. es_ES
dc.description.sponsorship This work was supported by the Natural Sciences and Engineering Research Council of Canada, the Canada Foundation for Innovation, the Canada Research Chairs Program and funding from Canada's International Development Research Centre (IDRC). Thanks are due to the RISE program for the scholarship awarded to M. C. and the Generalitat Valenciana (BEST/2017/049) for the financial support granted to M. L. M. The authors would like to thank Dr Yun Liu for helping on the acquisition of the SEM images. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation GV/BEST/2017/049 es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Glass wool: a novel support for heterogeneous catalysis es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8sc02115e es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Elhage, A.; Wang, B.; Marina, N.; Marín García, ML.; Cruz, M.; Lanterna, AE.; Scaiano, JC. (2018). Glass wool: a novel support for heterogeneous catalysis. Chemical Science. 9(33):6844-6852. https://doi.org/10.1039/c8sc02115e es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8sc02115e es_ES
dc.description.upvformatpinicio 6844 es_ES
dc.description.upvformatpfin 6852 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 33 es_ES
dc.identifier.pmid 30310617 es_ES
dc.identifier.pmcid PMC6114997 es_ES
dc.relation.pasarela S\379174 es_ES
dc.contributor.funder Canada Research Chairs es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Canada Foundation for Innovation es_ES
dc.contributor.funder International Development Research Centre, Canada es_ES
dc.contributor.funder Natural Sciences and Engineering Research Council of Canada es_ES


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