- -

Polymorphism and reverse spin transition in the spin crossover system [Co(4-terpyridone)2](CF3SO3)2·1H2O

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Polymorphism and reverse spin transition in the spin crossover system [Co(4-terpyridone)2](CF3SO3)2·1H2O

Mostrar el registro completo del ítem

Agustí, G.; Bartual-Murgui, C.; Martínez, V.; Muñoz-Lara, FJ.; Gaspar, AB.; Muñoz Roca, MDC.; Real, JA. (2009). Polymorphism and reverse spin transition in the spin crossover system [Co(4-terpyridone)2](CF3SO3)2·1H2O. New Journal of Chemistry. 33(6):1262-1267. https://doi.org/10.1039/b905674b

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/150428

Ficheros en el ítem

Metadatos del ítem

Título: Polymorphism and reverse spin transition in the spin crossover system [Co(4-terpyridone)2](CF3SO3)2·1H2O
Autor: Agustí, G. Bartual-Murgui, C. Martínez, V. Muñoz-Lara, F. J. Gaspar, A. B. Muñoz Roca, María Del Carmen Real, J. A.
Entidad UPV: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Fecha difusión:
Resumen:
[EN] Compound [Co(4-terpyridone)(2)](CF3SO3)(2)center dot 1H(2)O, where 4-terpyridone is 2,6-bis(2-pyridyl)-4(1H)-pyridone, forms two polymorphs. Polymorph 1 displays a continuous spin conversion in the temperature region ...[+]
Derechos de uso: Cerrado
Fuente:
New Journal of Chemistry. (issn: 1144-0546 )
DOI: 10.1039/b905674b
Editorial:
The Royal Society of Chemistry
Versión del editor: https://doi.org/10.1039/b905674b
Título del congreso: International Symposium on Molecular Materials. Chemistry, Solid State Physics,Theory, Nanotechnology. From Molecule to Molecular Device (MOLMAT 2008)
Lugar del congreso: Toulouse, Francia
Fecha congreso: Julio 08-11,2008
Código del Proyecto:
info:eu-repo/grantAgreement/MEC//CTQ2007-64727/ES/DISEÑO, SINTESIS Y NANO-ESTRUCTURACION DE MATERIALES MAGNETICOS DE BASE MOLECULAR CON TRANSICION DE ESPIN/
Agradecimientos:
Financial support from the Spanish Ministerio de Educacion y Ciencia (MEC) (CTQ 2007-64727) is acknowledged. A.B.G. thanks the Spanish MEC for a research contract (Programa Ramón y Cajal). We also acknowledge the European ...[+]
Tipo: Artículo Comunicación en congreso

References

Gütlich, P., Hauser, A., & Spiering, H. (1994). Thermal and Optical Switching of Iron(II) Complexes. Angewandte Chemie International Edition in English, 33(20), 2024-2054. doi:10.1002/anie.199420241

Real, J. A., Gaspar, A. B., Niel, V., & Muñoz, M. C. (2003). Communication between iron(II) building blocks in cooperative spin transition phenomena. Coordination Chemistry Reviews, 236(1-2), 121-141. doi:10.1016/s0010-8545(02)00220-5

Real, J. A., Gaspar, A. B., & Muñoz, M. C. (2005). Thermal, pressure and light switchable spin-crossover materials. Dalton Transactions, (12), 2062. doi:10.1039/b501491c [+]
Gütlich, P., Hauser, A., & Spiering, H. (1994). Thermal and Optical Switching of Iron(II) Complexes. Angewandte Chemie International Edition in English, 33(20), 2024-2054. doi:10.1002/anie.199420241

Real, J. A., Gaspar, A. B., Niel, V., & Muñoz, M. C. (2003). Communication between iron(II) building blocks in cooperative spin transition phenomena. Coordination Chemistry Reviews, 236(1-2), 121-141. doi:10.1016/s0010-8545(02)00220-5

Real, J. A., Gaspar, A. B., & Muñoz, M. C. (2005). Thermal, pressure and light switchable spin-crossover materials. Dalton Transactions, (12), 2062. doi:10.1039/b501491c

Garcia, Y., & Gütlich, P. (s. f.). Thermal Spin Crossover in Mn(II), Mn(III), Cr(II) and Co(III) Coordination Compounds. Spin Crossover in Transition Metal Compounds II, 49-62. doi:10.1007/b95412

Goodwin, H. A. (s. f.). Spin Crossover in Cobalt(II) Systems. Spin Crossover in Transition Metal Compounds II, 23-47. doi:10.1007/b95411

Kremer, S., Henke, W., & Reinen, D. (1982). High-spin-low-spin equilibriums of cobalt(2+) in the terpyridine complexes Co(terpy)2X2.nH2O. Inorganic Chemistry, 21(8), 3013-3022. doi:10.1021/ic00138a019

Figgis, B., Kucharski, E., & White, A. (1983). Crystal structure of Bis(2,2’:6’,2’’-terpyridyl)cobalt(II) perchlorate c. 1.3 hydrate. Australian Journal of Chemistry, 36(8), 1537. doi:10.1071/ch9831537

Zarembowitch, J., Claude, R., & Kahn, O. (1985). High-spin .tautm. low-spin transition in solid Co(H2fsa2en)(H2O)2[H4fsa2en = N,N’-ethylenebis(3-carboxysalicylaldimine)]: a magnetic investigation. Inorganic Chemistry, 24(10), 1576-1580. doi:10.1021/ic00204a033

Zarembowitch, J., & Kahn, O. (1984). Magnetic properties of some spin-crossover, high-spin, and low-spin cobalt(II) complexes with Schiff bases derived from 3-formylsalicylic acid. Inorganic Chemistry, 23(5), 589-593. doi:10.1021/ic00173a020

Thuery, P., & Zarembowitch, J. (1986). Spin state of cobalt(II) in five- and six-coordinate Lewis base adducts of N,N’-ethylenebis(3-carboxysalicylaldiminato)cobalt(II). New spin-crossover complexes. Inorganic Chemistry, 25(12), 2001-2008. doi:10.1021/ic00232a020

Faus, J., Julve, M., Lloret, F., Real, J. A., & Sletten, J. (1994). Dimethylvioluratobis(phenanthroline)cobalt(II), a Novel Spin-Crossover Octahedral Co(II) Complex. Synthesis, Crystal Structure and Magnetic Properties of [Co(dmvi)(phen)2]ClO4.cntdot.3H2O. Inorganic Chemistry, 33(24), 5535-5540. doi:10.1021/ic00102a030

Mizuno, K., & Lunsford, J. H. (1983). Electron paramagnetic resonance study of tris(2,2’-bipyridine)cobalt(II) complexes in zeolite Y: evidence for a spin equilibrium. Inorganic Chemistry, 22(23), 3484-3486. doi:10.1021/ic00165a025

Tiwary, S. K., & Vasudevan, S. (1998). Void Geometry Driven Spin Crossover in Zeolite-Encapsulated Cobalt Tris(bipyridyl) Complex Ion. Inorganic Chemistry, 37(20), 5239-5246. doi:10.1021/ic9711473

Sieber, R., Decurtins, S., Stoeckli-Evans, H., Wilson, C., Yufit, D., Howard, J. A. K., … Hauser, A. (2000). A Thermal Spin Transition in [Co(bpy)3][LiCr(ox)3] (ox=C2O42−; bpy=2,2′-bipyridine). Chemistry - A European Journal, 6(2), 361-368. doi:10.1002/(sici)1521-3765(20000117)6:2<361::aid-chem361>3.0.co;2-y

Brooker, S., Plieger, P. G., Moubaraki, B., & Murray, K. S. (1999). [CoII2L(NCS)2(SCN)2]: The First Cobalt Complex to Exhibit Both Exchange Coupling and Spin Crossover Effects. Angewandte Chemie International Edition, 38(3), 408-410. doi:10.1002/(sici)1521-3773(19990201)38:3<408::aid-anie408>3.0.co;2-p

Brooker, S., de Geest, D. J., Kelly, R. J., Plieger, P. G., Moubaraki, B., Murray, K. S., & Jameson, G. B. (2002). Exchange-coupled high-spin, low-spin and spin-crossover dicobalt(ii) complexes of a pyridazine-containing Schiff-base macrocycle: control of cobalt(ii) spin state by choice of axial ligands. Journal of the Chemical Society, Dalton Transactions, (9), 2080-2087. doi:10.1039/b111267h

Clérac, R., Cotton, F. A., Daniels, L. M., Dunbar, K. R., Kirschbaum, K., Murillo, C. A., … Wang, X. (2000). Linear Tricobalt Compounds with Di(2-pyridyl)amide (dpa) Ligands:  Temperature Dependence of the Structural and Magnetic Properties of Symmetrical and Unsymmetrical Forms of Co3(dpa)4Cl2in the Solid State. Journal of the American Chemical Society, 122(26), 6226-6236. doi:10.1021/ja000515q

Clérac, R., Cotton, F. A., Daniels, L. M., Dunbar, K. R., Murillo, C. A., & Wang, X. (2001). Tuning the Metal−Metal Bonds in the Linear Tricobalt Compound Co3(dpa)4Cl2:  Bond-Stretch and Spin-State Isomers. Inorganic Chemistry, 40(6), 1256-1264. doi:10.1021/ic001068i

Clérac, R., Cotton, F. A., Dunbar, K. R., Lu, T., Murillo, C. A., & Wang, X. (2000). A New Linear Tricobalt Compound with Di(2-pyridyl)amide (dpa) Ligands:  Two-Step Spin Crossover of [Co3(dpa)4Cl2][BF4]. Journal of the American Chemical Society, 122(10), 2272-2278. doi:10.1021/ja994051b

Hayami, S., Hashiguchi, K., Juhász, G., Ohba, M., Ōkawa, H., Maeda, Y., … Inoue, K. (2004). 1-D Cobalt(II) Spin Transition Compound with Strong Interchain Interaction:  [Co(pyterpy)Cl2]·X. Inorganic Chemistry, 43(14), 4124-4126. doi:10.1021/ic049509b

Gaspar, A. B., Muñoz, M. C., Niel, V., & Real, J. A. (2001). [CoII(4-terpyridone)2]X2:  A Novel Cobalt(II) Spin Crossover System [4-Terpyridone = 2,6-Bis(2-pyridyl)-4(1H)-pyridone]. Inorganic Chemistry, 40(1), 9-10. doi:10.1021/ic000788m

Galet, A., Gaspar, A. B., Muñoz, M. C., & Real, J. A. (2006). Influence of the Counterion and the Solvent Molecules in the Spin Crossover System [Co(4-terpyridone)2]Xp·nH2O. Inorganic Chemistry, 45(11), 4413-4422. doi:10.1021/ic060090u

Hayami, S., Shigeyoshi, Y., Akita, M., Inoue, K., Kato, K., Osaka, K., … Maeda, Y. (2005). Reverse Spin Transition Triggered by a Structural Phase Transition. Angewandte Chemie International Edition, 44(31), 4899-4903. doi:10.1002/anie.200500316

Hayami, S., Moriyama, R., Shigeyoshi, Y., Kawajiri, R., Mitani, T., Akita, M., … Maeda, Y. (2005). Spin-Crossover Cobalt(II) Compound with Banana-Shaped Structure. Inorganic Chemistry, 44(21), 7295-7297. doi:10.1021/ic051059f

Hayami, S., Moriyama, R., Shuto, A., Maeda, Y., Ohta, K., & Inoue, K. (2007). Spin Transition at the Mesophase Transition Temperature in a Cobalt(II) Compound with Branched Alkyl Chains. Inorganic Chemistry, 46(19), 7692-7694. doi:10.1021/ic700754s

Seredyuk, M., Gaspar, A. B., Ksenofontov, V., Galyametdinov, Y., Kusz, J., & Gütlich, P. (2008). Iron(II) Metallomesogens Exhibiting Coupled Spin State and Liquid Crystal Phase Transitions near Room Temperature. Advanced Functional Materials, 18(14), 2089-2101. doi:10.1002/adfm.200800049

Davey, R. J. (2003). Pizzas, polymorphs and pills. Chemical Communications, (13), 1463. doi:10.1039/b303125j

Dunitz, J. D., & Bernstein, J. (1995). Disappearing Polymorphs. Accounts of Chemical Research, 28(4), 193-200. doi:10.1021/ar00052a005

Real, J. A., Gallois, B., Granier, T., Suez-Panama, F., & Zarembowitch, J. (1992). Comparative investigation of the spin-crossover compounds Fe(btz)2(NCS)2 and Fe(phen)2(NCS)2 (where btz = 2,2’-bi-4,5-dihydrothiazine and phen = 1,10-phenanthroline). Magnetic properties and thermal dilatation behavior and crystal structure of Fe(btz)2(NCS)2 at 293 and 130 K. Inorganic Chemistry, 31(24), 4972-4979. doi:10.1021/ic00050a013

Törnroos, K. W., Hostettler, M., Chernyshov, D., Vangdal, B., & Bürgi, H.-B. (2006). Interplay of Spin Conversion and Structural Phase Transformations: Re-Entrant Phase Transitions in the 2-Propanol Solvate of Tris(2-picolylamine)iron(II) Dichloride. Chemistry - A European Journal, 12(24), 6207-6215. doi:10.1002/chem.200600547

[-]

recommendations

 

Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro completo del ítem