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dc.contributor.author | Mateo-Mateo, Diego | es_ES |
dc.contributor.author | Santiago-Portillo, Andrea | es_ES |
dc.contributor.author | Albero-Sancho, Josep | es_ES |
dc.contributor.author | Navalón Oltra, Sergio | es_ES |
dc.contributor.author | Alvaro Rodríguez, Maria Mercedes | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.date.accessioned | 2020-10-28T04:32:44Z | |
dc.date.available | 2020-10-28T04:32:44Z | |
dc.date.issued | 2019-12-02 | es_ES |
dc.identifier.issn | 1433-7851 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/153361 | |
dc.description | This is the peer reviewed version of the following article: Mateo, Diego, et al. Long-Term Photostability in Terephthalate Metal-Organic Frameworks. Angewandte Chemie (International Ed.), vol. 58, no. 49, Wiley, 2019, pp. 17843 48, doi:10.1002/anie.201911600, which has been published in final form at https://doi.org/10. 1002/anie.201911600. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | es_ES |
dc.description.abstract | [EN] Prolonged (weeks) UV/Vis irradiation under Ar of UiO-66(Zr), UiO66 Zr-NO2, MIL101 Fe, MIL125 Ti-NH2, MIL101 Cr and MIL101 Cr(Pt) shows that these MOFs undergo photodecarboxylation of benzenedicarboxylate (BDC) linker in a significant percentage depending on the structure and composition of the material. Routine characterization techniques such as XRD, UV/Vis spectroscopy and TGA fail to detect changes in the material, although porosity and surface area change upon irradiation of powders. In contrast to BCD-containing MOFs, zeolitic imidazolate ZIF-8 does not evolve CO2 or any other gas upon irradiation. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa, and CTQ2015-69563-CO2-R1) and by the Generalitat Valenciana (Prometeo 2013-014) is gratefully acknowledged. J.A. thanks the Universitat Politecnica de Valencia for a postdoctoral scholarship. D.M. also thanks Spanish Ministry of Science for PhD Scholarship. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation | MINECO/CTQ2015-69563-CO2-R1 | es_ES |
dc.relation.ispartof | Angewandte Chemie International Edition | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | CO2 evolution | es_ES |
dc.subject | Long-term stability | es_ES |
dc.subject | Metal-organic frameworks | es_ES |
dc.subject | Photocatalysis | es_ES |
dc.subject | Photodecarboxylation | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Long-Term Photostability in Terephthalate Metal-Organic Frameworks | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/anie.201911600 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2013%2F014/ES/SINTESIS DE GRAFENO Y DERIVADOS COMO SENSORES O CON PROPIEDADES OPTOELECTRONICAS/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Mateo-Mateo, D.; Santiago-Portillo, A.; Albero-Sancho, J.; Navalón Oltra, S.; Alvaro Rodríguez, MM.; García Gómez, H. (2019). Long-Term Photostability in Terephthalate Metal-Organic Frameworks. Angewandte Chemie International Edition. 58(49):17843-17848. https://doi.org/10.1002/anie.201911600 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/anie.201911600 | es_ES |
dc.description.upvformatpinicio | 17843 | es_ES |
dc.description.upvformatpfin | 17848 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 58 | es_ES |
dc.description.issue | 49 | es_ES |
dc.identifier.pmid | 31584744 | es_ES |
dc.relation.pasarela | S\407065 | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |