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Zr-MOF-808@MCM-41 catalyzed phosgene-free synthesis of polyurethane precursors

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Zr-MOF-808@MCM-41 catalyzed phosgene-free synthesis of polyurethane precursors

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dc.contributor.author Rojas-Buzo, Sergio es_ES
dc.contributor.author García-García, Pilar es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2020-11-10T04:33:05Z
dc.date.available 2020-11-10T04:33:05Z
dc.date.issued 2019-01-07 es_ES
dc.identifier.issn 2044-4753 es_ES
dc.identifier.uri http://hdl.handle.net/10251/154505
dc.description.abstract [EN] In this work, a catalytic method is presented for the synthesis of aromatic carbamates from aromatic amines using dimethyl carbonate instead of phosgene as a green and safe reaction process. Microcrystalline Zr-MOF-808 is reported as an active and efficient heterogeneous catalyst for the selective carbamoylation of anilines and industrially relevant aromatic diamines, under mild reaction conditions with near quantitative yields. We have accomplished the selective growth of well-dispersed Zr-MOF-808 nanocrystals within the mesoporous material MCM-41. A superior catalytic performance of the Zr-MOF808@MCM-41 is demonstrated that together with increased stability stands out as an advantageous heterogeneous catalyst for polyurethane production. In situ FTIR studies have allowed a better understanding of the reaction pathway at the molecular level when the active MOF catalyst is present. es_ES
dc.description.sponsorship This work was funded by the European Union through the European Research Council (grant ERC-AdG-2014-671093, SynCatMatch) and by the Spanish government through the Severo Ochoa program (SEV-2016-0683). S.R.-B. acknowledges a PhD fellowship from the Generalitat Valenciana. The Electron Microscopy Service of the Universitat Politecnica de Valenciais acknowledged for their help in sample characterization. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science & Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Zr-MOF-808@MCM-41 catalyzed phosgene-free synthesis of polyurethane precursors es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8cy02235f es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Rojas-Buzo, S.; García-García, P.; Corma Canós, A. (2019). Zr-MOF-808@MCM-41 catalyzed phosgene-free synthesis of polyurethane precursors. Catalysis Science & Technology. 9(1):146-156. https://doi.org/10.1039/c8cy02235f es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8cy02235f es_ES
dc.description.upvformatpinicio 146 es_ES
dc.description.upvformatpfin 156 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 1 es_ES
dc.relation.pasarela S\387435 es_ES
dc.contributor.funder European Research Council es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder European Commission
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