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Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis

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Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis

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dc.contributor.author Liu, Lichen es_ES
dc.contributor.author Lopez-Haro, Miguel es_ES
dc.contributor.author Lopes, Christian W. es_ES
dc.contributor.author Li, Chengeng es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Simonelli, Laura es_ES
dc.contributor.author Calvino, Jose J. es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2021-01-21T04:31:42Z
dc.date.available 2021-01-21T04:31:42Z
dc.date.issued 2019-08 es_ES
dc.identifier.issn 1476-1122 es_ES
dc.identifier.uri http://hdl.handle.net/10251/159599
dc.description.abstract [EN] Subnanometric metal species (single atoms and clusters) have been demonstrated to be unique compared with their nanoparticulate counterparts. However, the poor stabilization of subnanometric metal species towards sintering at high temperature (>500 degrees C) under oxidative or reductive reaction conditions limits their catalytic application. Zeolites can serve as an ideal support to stabilize subnanometric metal catalysts, but it is challenging to localize subnanometric metal species on specific sites and modulate their reactivity. We have achieved a very high preference for localization of highly stable subnanometric Pt and PtSn clusters in the sinusoidal channels of purely siliceous MFI zeolite, as revealed by atomically resolved electron microscopy combining high-angle annular dark-field and integrated differential phase contrast imaging techniques. These catalysts show very high stability, selectivity and activity for the industrially important dehydrogenation of propane to form propylene. This stabilization strategy could be extended to other crystalline porous materials. es_ES
dc.description.sponsorship This work has been supported by the European Union through the European Research Council (grant ERC-AdG-2014-671093, SynCatMatch) and the Spanish government through the Severo Ochoa Programme (SEV-2016-0683). L.L. thanks ITQ for providing a contract. The authors also thank the Microscopy Service of UPV for the TEM and STEM measurements. The XAS measurements were carried out in CLAESS beamline at the ALBA synchrotron. HR STEM measurements were performed at DME-UCA in Cadiz University with financial support from FEDER/MINECO (MAT2017-87579-R and MAT2016-81118-P). A relevant patent application (European patent application No. 19382024.8) has been presented. C.W.L. thanks CAPES (Science without Frontiers-Process no. 13191/13-6) for a predoctoral fellowship. es_ES
dc.language Inglés es_ES
dc.publisher Nature Publishing Group es_ES
dc.relation.ispartof Nature Materials es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1038/s41563-019-0412-6 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAPES//13191%2F13-6/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-87579-R/ES/FASES 2D ULTRAFINAS SOBRE OXIDOS CON MORFOLOGIA CONTROLADA: PLATAFORMA DE NANOCATALIZADORES MULTICOMPONENTE CON APLICACIONES EN PROTECCION DEL MEDIO AMBIENTE/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-81118-P/ES/DISEÑO Y CARACTERIZACION AVANZADA DE CATALIZADORES CON NANOINTERFASES MODELO AU%2F%2FCEO2/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Liu, L.; Lopez-Haro, M.; Lopes, CW.; Li, C.; Concepción Heydorn, P.; Simonelli, L.; Calvino, JJ.... (2019). Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis. Nature Materials. 18(8):866-875. https://doi.org/10.1038/s41563-019-0412-6 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1038/s41563-019-0412-6 es_ES
dc.description.upvformatpinicio 866 es_ES
dc.description.upvformatpfin 875 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 18 es_ES
dc.description.issue 8 es_ES
dc.identifier.pmid 31263227 es_ES
dc.relation.pasarela S\410698 es_ES
dc.contributor.funder European Research Council es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Commission
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