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Defect-Engineered Ruthenium MOFs as Versatile Heterogeneous Hydrogenation Catalysts

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Defect-Engineered Ruthenium MOFs as Versatile Heterogeneous Hydrogenation Catalysts

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dc.contributor.author Epp, Konstantin es_ES
dc.contributor.author Luz, Ignacio es_ES
dc.contributor.author Heinz, Werner R. es_ES
dc.contributor.author Rapeyko, Anastasia es_ES
dc.contributor.author Llabrés i Xamena, Francesc Xavier es_ES
dc.contributor.author Fischer, Roland A. es_ES
dc.date.accessioned 2021-04-17T03:33:09Z
dc.date.available 2021-04-17T03:33:09Z
dc.date.issued 2020-03-19 es_ES
dc.identifier.issn 1867-3880 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165293
dc.description.abstract [EN] Ruthenium MOF [Ru-3(BTC)(2)Y-y] . G(g) (BTC=benzene-1,3,5-tricarboxylate; Y=counter ions=Cl-, OH-, OAc-; G=guest molecules=HOAc, H2O) is modified via a mixed-linker approach, using mixtures of BTC and pyridine-3,5-dicarboxylate (PYDC) linkers, triggering structural defects at the distinct Ru-2 paddlewheel (PW) nodes. This defect-engineering leads to enhanced catalytic properties due to the formation of partially reduced Ru-2-nodes. Application of a hydrogen pre-treatment protocol to the Ru-MOFs, leads to a further boost in catalytic activity. We study the benefits of (1) defect engineering and (2) hydrogen pre-treatment on the catalytic activity of Ru-MOFs in the Meerwein-Ponndorf-Verley reaction and the isomerization of allylic alcohols to saturated ketones. Simple solvent washing could not avoid catalyst deactivation during recycling for the latter reaction, while hydrogen treatment prior to each catalytic run proved to facilitate materials recyclability with constant activity over five runs. es_ES
dc.description.sponsorship Funding by the Spanish Government is acknowledged through projects MAT2017-82288-C2-1-P and Severo Ochoa (SEV-2016-0683). This project is further funded by the Deutsche Forschungsgemeinschaft grant no. FI-502/32-1 ("DEMOFs"). KE and WRH would like to thank TUM Graduate School and the Gesellschaft Deutscher Chemiker (GDCh) for financial support. KE gratefully acknowledges support from the colleagues Olesia Halbherr (nee Kozachuk) and Wenhua Zhang. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Metal-Organic Frameworks es_ES
dc.subject Defects es_ES
dc.subject Ruthenium es_ES
dc.subject Ru-BTC es_ES
dc.subject Ru-MOF es_ES
dc.subject HKUST-1 es_ES
dc.subject Defect-Engineering es_ES
dc.subject MOF catalysis es_ES
dc.subject DEMOF es_ES
dc.title Defect-Engineered Ruthenium MOFs as Versatile Heterogeneous Hydrogenation Catalysts es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/cctc.201902079 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DFG//FI-502%2F32-1/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Epp, K.; Luz, I.; Heinz, WR.; Rapeyko, A.; Llabrés I Xamena, FX.; Fischer, RA. (2020). Defect-Engineered Ruthenium MOFs as Versatile Heterogeneous Hydrogenation Catalysts. ChemCatChem. 12(6):1720-1725. https://doi.org/10.1002/cctc.201902079 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/cctc.201902079 es_ES
dc.description.upvformatpinicio 1720 es_ES
dc.description.upvformatpfin 1725 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 6 es_ES
dc.relation.pasarela S\409743 es_ES
dc.contributor.funder Deutsche Forschungsgemeinschaft es_ES
dc.contributor.funder Gesellschaft Deutscher Chemiker es_ES
dc.contributor.funder Technische Universität München es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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