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Ferrierite and Its Delaminated and Silica-Intercalated Forms Modified with Copper as Effective Catalysts for NH3-SCR Process

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Ferrierite and Its Delaminated and Silica-Intercalated Forms Modified with Copper as Effective Catalysts for NH3-SCR Process

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dc.contributor.author Swies, Aneta es_ES
dc.contributor.author Kowalczyk, Andrzej es_ES
dc.contributor.author Rutkowska, Malgorzata es_ES
dc.contributor.author DÍAZ MORALES, URBANO MANUEL es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.contributor.author Chmielarz, Lucjan es_ES
dc.date.accessioned 2021-04-29T03:32:09Z
dc.date.available 2021-04-29T03:32:09Z
dc.date.issued 2020-07 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165768
dc.description.abstract [EN] The main goal of the study was the development of effective catalysts for the low-temperature selective catalytic reduction of NO with ammonia (NH3-SCR), based on ferrierite (FER) and its delaminated (ITQ-6) and silica-intercalated (ITQ-36) forms modified with copper. The copper exchange zeolitic samples, with the intended framework Si/Al ratio of 30 and 50, were synthetized and characterized with respect to their chemical composition (ICP-OES), structure (XRD), texture (low-temperature N(2)adsorption), form and aggregation of deposited copper species (UV-vis-DRS), surface acidity (NH3-TPD) and reducibility (H-2-TPR). The samples of the Cu-ITQ-6 and Cu-ITQ-36 series were found to be significantly more active NH3-SCR catalysts compared to Cu-FER. The activity of these catalysts in low-temperature NH3-SCR was assigned to the significant contribution of highly dispersed copper species (monomeric cations and small oligomeric species) catalytically active in the oxidation of NO to NO(2,)which is necessary for fast-SCR. The zeolitic catalysts, with the higher framework alumina content, were more effective in high-temperature NH3-SCR due to their limited catalytic activity in the side reaction of ammonia oxidation. es_ES
dc.description.sponsorship This work was supported by the National Science Centre-Poland [2016/21/B/ST5/00242]. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Catalysts es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject NH3-SCR es_ES
dc.subject Ferrierite es_ES
dc.subject ITQ-6 es_ES
dc.subject ITQ-36 es_ES
dc.subject Copper es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Ferrierite and Its Delaminated and Silica-Intercalated Forms Modified with Copper as Effective Catalysts for NH3-SCR Process es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/catal10070734 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NCN//2016%2F21%2FB%2FST5%2F00242/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Swies, A.; Kowalczyk, A.; Rutkowska, M.; Díaz Morales, UM.; Palomares Gimeno, AE.; Chmielarz, L. (2020). Ferrierite and Its Delaminated and Silica-Intercalated Forms Modified with Copper as Effective Catalysts for NH3-SCR Process. Catalysts. 10(7):1-21. https://doi.org/10.3390/catal10070734 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/catal10070734 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 21 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 7 es_ES
dc.identifier.eissn 2073-4344 es_ES
dc.relation.pasarela S\434269 es_ES
dc.contributor.funder National Science Centre, Polonia es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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