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Effect of Ionic Liquid Content on the Crystallization Kinetics and Morphology of Semicrystalline Poly(vinylidene Fluoride)/Ionic Liquid Blends

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Effect of Ionic Liquid Content on the Crystallization Kinetics and Morphology of Semicrystalline Poly(vinylidene Fluoride)/Ionic Liquid Blends

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dc.contributor.author Correia, Daniela M. es_ES
dc.contributor.author Costa, Carlos M. es_ES
dc.contributor.author Rodriguez-Hernandez, Jose-Carlos es_ES
dc.contributor.author Tort-Ausina, Isabel es_ES
dc.contributor.author Teruel Biosca, Laura es_ES
dc.contributor.author Torregrosa Cabanilles, Constantino es_ES
dc.contributor.author Meseguer Dueñas, José María es_ES
dc.contributor.author Lanceros-Méndez, Senentxu es_ES
dc.contributor.author Gómez Ribelles, José Luís es_ES
dc.date.accessioned 2021-04-30T03:31:30Z
dc.date.available 2021-04-30T03:31:30Z
dc.date.issued 2020-08-05 es_ES
dc.identifier.issn 1528-7483 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165800
dc.description.abstract [EN] The crystallization kinetics of poly(vinylidene fluoride) (PVDF) in blends with the ionic liquid (IL) 1-ethyl-3-methylimidazolium chloride [Emim][Cl] has been studied as a function of [Emim][Cl] content up to 40 wt %. Blends were produced by a solvent casting technique from diluted solutions and solvent evaporation at a temperature higher than the melting point of PVDF followed by cooling to room temperature. Polymer phase, morphology, and crystallization behavior were evaluated. When the molten blend was crystallized from the melt, it was observed that [Emim][Cl] induces nucleation of PVDF in the electroactive and highly polar beta-crystalline phase, while pure PVDF crystallizes in the a phase with the same thermal treatments. It is shown that PVDF crystal growth segregates an amorphous phase rich in IL molecules to the surface of the films and that the IL also remains in the spaces between the lamellae or between spherulites as demonstrated by scanning electronic microscopy (SEM) and polarizing optical microscope (POM) images. Differential scanning calorimetry results of isothermal crystallization show the dependence of equilibrium melting temperature and the Avrami exponent with the [Emim][Cl] content. es_ES
dc.description.sponsorship This work was supported by the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Funding UID/FIS/04650/2020. The authors thank FEDER funds through the COMPETE 2020 Programme and National Funds through FCT under the Projects PTDC/BTM-MAT/28237/2017, PTDC/EMD-EMD/28159/2017, and PTDC/FIS-MAC/28157/2017. D.M.C. and C.M.C. also thank to the FCT for grants SFRH/BPD/121526/2016 and SFRH/BPD/112547/2015, respectively. Financial support from the Spanish Ministry of Economy and Competitiveness (MINECO) through the Project MAT2016-76039-C4-1 -R (AEI/FEDER, UE) (including the FEDER financial support), from the Spanish State Research Agency (AEI) and the European Regional Development Fund (ERFD) through the project PID2019-106099RB-C43/AEI/10.13039/501100011033 and from the Basque Government Industry and Education Departments under the ELKARTEK, HAZ-ITEK, and PIBA (PIBA-2018-06) programs, respectively, are acknowledged. CIBER-BBN is an initiative funded by the VI National R&D&I Plan 2008-2011, Iniciativa Ingenio 2010, Consolider Program. CIBER Actions are financed by the Instituto de Salud Carlos III with assistance from the European Regional Development Fund. es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Crystal Growth & Design es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Salts es_ES
dc.subject Melting es_ES
dc.subject Crystallization es_ES
dc.subject Fluoropolymers es_ES
dc.subject Solvents es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Effect of Ionic Liquid Content on the Crystallization Kinetics and Morphology of Semicrystalline Poly(vinylidene Fluoride)/Ionic Liquid Blends es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acs.cgd.0c00042 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/3599-PPCDT/121526/PT/Heterometallic Metal-organic Frameworks: Smart Materials for Advanced Applications/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/FCT%2FSFRH%2FBPD%2F112547%2F2015/PT/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F28159%2F2006/PT/MOLECULAR MECHANISM OF HEALING, REPAIR AND REGENERATION IN VERTEBRATES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT//UID%2FFIS%2F04650%2F2020/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT//SFRH%2FBPD%2F121526%2F2016/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT//PTDC%2FFIS-MAC%2F28157%2F2017/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT//PTDC%2FEMD-EMD%2F28159%2F2017/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT//PTDC%2FBTM-MAT%2F28237%2F2017/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Eusko Jaurlaritza//PIBA-2018-06/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-106099RB-C41/ES/MICROGELES BIOMIMETICOS PARA EL ESTUDIO DE LA GENERACION DE RESISTENCIAS A FARMACOS EN EL MIELOMA MULTIPLE./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-76039-C4-1-R/ES/BIOMATERIALES PIEZOELECTRICOS PARA LA DIFERENCIACION CELULAR EN INTERFASES CELULA-MATERIAL ELECTRICAMENTE ACTIVAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Correia, DM.; Costa, CM.; Rodriguez-Hernandez, J.; Tort-Ausina, I.; Teruel Biosca, L.; Torregrosa Cabanilles, C.; Meseguer Dueñas, JM.... (2020). Effect of Ionic Liquid Content on the Crystallization Kinetics and Morphology of Semicrystalline Poly(vinylidene Fluoride)/Ionic Liquid Blends. Crystal Growth & Design. 20(8):4967-4979. https://doi.org/10.1021/acs.cgd.0c00042 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acs.cgd.0c00042 es_ES
dc.description.upvformatpinicio 4967 es_ES
dc.description.upvformatpfin 4979 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 20 es_ES
dc.description.issue 8 es_ES
dc.relation.pasarela S\424137 es_ES
dc.contributor.funder Instituto de Salud Carlos III es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Gobierno Vasco/Eusko Jaurlaritza es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Fundação para a Ciência e a Tecnologia, Portugal es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Centro de Investigación Biomédica en Red en Bioingeniería, Biomateriales y Nanomedicina es_ES
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