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Evidence of a new phase in gypsum-anhydrite transformations under microwave heating by in situ dielectric analysis and Raman spectroscopy

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Evidence of a new phase in gypsum-anhydrite transformations under microwave heating by in situ dielectric analysis and Raman spectroscopy

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dc.contributor.author López-Buendía, Angel M. es_ES
dc.contributor.author García-Baños, Beatriz es_ES
dc.contributor.author Urquiola, M. Mar es_ES
dc.contributor.author Catalá Civera, José Manuel es_ES
dc.contributor.author Penaranda-Foix, Felipe L. es_ES
dc.date.accessioned 2021-05-27T03:34:57Z
dc.date.available 2021-05-27T03:34:57Z
dc.date.issued 2020-12-21 es_ES
dc.identifier.issn 1463-9076 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166839
dc.description.abstract [EN] Mineral transformations of the gypsum-anhydrite system under microwave heating have been studied using in situ dielectric thermal analysis (MW-DETA) and Raman spectroscopy simultaneously. The dielectric properties of samples that were measured under microwave heating provided thorough information about the dynamics of the gypsum-anhydrite system transformations and its significance from the mineralogical point of view. In particular, the MW-DETA technique revealed a new intermediate phase with a gamma-anhydrite structure. This phase corresponds to the soluble stage of gamma-anhydrite, and it is characterized by a high ionic charge inside the crystal channels. The complete sequence is gypsum -> 0.625-subhydrate -> bassanite -> hydro gamma-anhydrite -> anhydrous gamma-anhydrite -> beta-anhydrite. The transformations were also assessed using DSC, TG, DTA and dielectric measurements at room temperature, as well as other techniques including X-ray powder diffraction (XRPD) and high-temperature XRD (HT-XRD). Correlations between the dielectric properties with temperature and the rest of the techniques elucidated the heating mechanisms of this material under microwave energy during the different stages. The in situ combination of the MW-DETA and the Raman analysis appears to be a powerful technique, providing new insights about the mechanisms which govern the volumetric heating of this and other materials. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Physical Chemistry Chemical Physics es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject.classification TEORIA DE LA SEÑAL Y COMUNICACIONES es_ES
dc.title Evidence of a new phase in gypsum-anhydrite transformations under microwave heating by in situ dielectric analysis and Raman spectroscopy es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0cp04926c es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Comunicaciones - Departament de Comunicacions es_ES
dc.description.bibliographicCitation López-Buendía, AM.; García-Baños, B.; Urquiola, MM.; Catalá Civera, JM.; Penaranda-Foix, FL. (2020). Evidence of a new phase in gypsum-anhydrite transformations under microwave heating by in situ dielectric analysis and Raman spectroscopy. Physical Chemistry Chemical Physics. 22(47):27713-27723. https://doi.org/10.1039/d0cp04926c es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0cp04926c es_ES
dc.description.upvformatpinicio 27713 es_ES
dc.description.upvformatpfin 27723 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 22 es_ES
dc.description.issue 47 es_ES
dc.identifier.pmid 33242036 es_ES
dc.relation.pasarela S\432733 es_ES
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