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Synthesis, Structure, Reactivity and Catalytic Implications of a Cationic, Acetylide-Bridged Trigold-JohnPhos Species

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Synthesis, Structure, Reactivity and Catalytic Implications of a Cationic, Acetylide-Bridged Trigold-JohnPhos Species

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Grirrane, A.; Álvarez, E.; García Gómez, H.; Corma Canós, A. (2020). Synthesis, Structure, Reactivity and Catalytic Implications of a Cationic, Acetylide-Bridged Trigold-JohnPhos Species. Chemistry - A European Journal. 26(40):8810-8818. https://doi.org/10.1002/chem.202000420

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Title: Synthesis, Structure, Reactivity and Catalytic Implications of a Cationic, Acetylide-Bridged Trigold-JohnPhos Species
Author: Grirrane, Abdessamad Álvarez, Eleuterio García Gómez, Hermenegildo Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] The cationic complex [(JohnPhos-Au)(3)(acetylide)][SbF6] (JohnPhos=(2-biphenyl)di-tert-butylphosphine, L1) has been characterised structurally and features an acetylide-trigold(I)-JohnPhos system; the trinuclear-acetylide ...[+]
Subjects: Acetals , Gold , Homogeneous catalysis , Multinuclear complexes , Phosphorus , Reaction mechanisms
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.202000420
Publisher:
John Wiley & Sons
Publisher version: https://doi.org/10.1002/chem.202000420
Project ID:
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/
info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F017/
MINECO/RTI2018-89027-CO2-R1
Thanks:
Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and RTI2018-89027-CO2-R1) and the Generalitat Valenciana (Prometeo 2013-2014) is gratefully acknowledged.
Type: Artículo

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