- -

Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Tailoring porous ...
Tamaño: 1.032Mb
Formato: PDF
Descripción: Versión del Autor.
Abrir
[Cerrado]
Nombre: CaliforniaEurPoly ...
Tamaño: 974.9Kb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author California, António es_ES
dc.contributor.author Cardoso, Vanessa F. es_ES
dc.contributor.author Costa, Carlos M. es_ES
dc.contributor.author Sencadas, Vitor es_ES
dc.contributor.author Botelho, Gabriela es_ES
dc.contributor.author Gómez Ribelles, José Luís es_ES
dc.contributor.author Lanceros-Mendez, Senentxu
dc.date.accessioned 2013-09-06T11:49:33Z
dc.date.issued 2011
dc.identifier.issn 0014-3057
dc.identifier.uri http://hdl.handle.net/10251/31823
dc.description.abstract Ferroelectric macroporous poly(vinylidene fluoride-trifluoroethylene) membranes have been produced by isothermal crystallization from the solution at different temperatures starting from different diluted solutions of the co-polymer in dimethylformamide. In this way pore architecture, consisting in interconnected spherical pores can be obtained. The mechanism and kinetics of solvent evaporation was investigated and related to the evolution of the polymer microstructure. The mechanism underlying the pattern formation has been discussed on the light of the Flory-Huggins (FH) lattice theory, grain boundary effects and the Cahn-Hilliard equation for mass conservation systems. It was also observed that the temperature or initial concentration of the crystallization process does not affect the phase, ferroelectric transition temperature or the melting temperature of the polymer. es_ES
dc.description.sponsorship The authors thank the Portuguese Foundation for Science and Technology (FCT) Grants PTDC/CTM-NAN/112574/2009, PTDC/CTM/73030/2006, PTDC/CTM/69316/2006 and NANO/NMed-SD/0156/2007. V.F., C.M.C. and V.S. thank the FCT for the SFRH/BD/44289/2008, SFRH/BD/68499/2010, SFRH/BPD/63148/2009 grants, respectively. JLGR acknowledge the funding from the Programa de Apoyo a la Investigacion y Desarrollo (PAID-00-09) of the Universidad Politecnica de Valencia for a short stay in Universidade do Minho, Braga, the support of the Spanish Ministry of Science through project No. MAT2010-21611-C03-01 (including the FEDER financial support) and funding for research in the field of Regenerative Medicine through the collaboration agreement from the Conselleria de Sanidad (Generalitat Valenciana), and the Institute de Salud Carlos III (Ministry of Science and Innovation). The authors wish also thank the CeNTI - Centre for Nanotechnology and Smart Materials, Rua Fernando Mesquita, 2782, 4760-034 Vila Nova de Famalicao, Portugal for allowing the use of some experimental equipment. en_EN
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof EUROPEAN POLYMER JOURNAL es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Electroactive membranes es_ES
dc.subject Porous membranes es_ES
dc.subject PVDF es_ES
dc.subject Solvent evaporation es_ES
dc.subject Phase diagram es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1016/j.eurpolymj.2011.10.005
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/SFRH/BD/44289/2008/PT/ en_EN
dc.relation.projectID info:eu-repo/grantAgreement/Gobierno de la Comunidad de Madrid//99%2F2010/ES/Entrenamiento cognitivo para el fomento del uso de las TICs: Rompiendo la brecha Digital/ / es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-00-09/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/SFRH/BD/68499/2010/PT/
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2010-21611-C03-01/ES/MATERIALES BIOESTABLES Y BIOREABSORBIBLES A LARGO PLAZO COMO SOPORTES MACROPOROSOS PARA LA REGENERACION DEL CARTILAGO ARTICULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/SFRH/BPD/63148/2009/PT/
dc.relation.projectID info:eu-repo/grantAgreement/Gobierno de la Comunidad de Madrid//9%2F2010/ES/EcoSistemaIP con Control Remoto Web de Suministros Combustibles y dispositivos en Gasolineras/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/5876-PPCDTI/112574/PT/PROTSENSOR - A novel pressure sensor network system for static and dynamic measurement. Application to the limb/prosthesis pressure mapping./
dc.relation.projectID info:eu-repo/grantAgreement/Junta de Comunidades de Castilla-La Mancha//99%2F2010/ES/99%2F2010/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/5876-PPCDTI/73030/PT/Polarization-driven self-assembly of organic and biomaterials using ferroelectric polymers/
dc.relation.projectID info:eu-repo/grantAgreement/FCT/5876-PPCDTI/69316/PT/Multiferroic, magnetoelectric and metallic micro and nanocomposites based on electroactive polymers for advanced applications/
dc.relation.projectID info:eu-repo/grantAgreement/FCT/5876-PPCDTI/109368/PT/“Smart joint implants using bionanocomposites-(SIMBIO)”/
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation California, A.; Cardoso, VF.; Costa, CM.; Sencadas, V.; Botelho, G.; Gómez Ribelles, JL.; Lanceros-Mendez, S. (2011). Tailoring porous structure of ferroelectric poly(vinylidene fluoride-trifluoroethylene) by controlling solvent/polymer ratio and solvent evaporation rate. EUROPEAN POLYMER JOURNAL. 47(12):2442-2450. https://doi.org/10.1016/j.eurpolymj.2011.10.005 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1016/j.eurpolymj.2011.10.005 es_ES
dc.description.upvformatpinicio 2442 es_ES
dc.description.upvformatpfin 2450 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 47 es_ES
dc.description.issue 12 es_ES
dc.relation.senia 212297
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Instituto de Salud Carlos III es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Fundação para a Ciência e a Tecnologia, Portugal


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem