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dc.contributor.author | Amarajothi, Dhakshinamoorthy | es_ES |
dc.contributor.author | Alvaro Rodríguez, Maria Mercedes | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.date.accessioned | 2013-09-11T06:37:12Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1359-7345 | |
dc.identifier.uri | http://hdl.handle.net/10251/31960 | |
dc.description.abstract | Metal¿organic frameworks (MOFs) are porous crystalline materials that have promising applications as heterogeneous catalysts. After describing the composition, textural properties and crystal structure of four commercially available MOFs, we summarize organic transformations for which these commercial MOFs exhibit higher catalytic activity than the corresponding soluble metal salts or metal ion-exchanged zeolites. In the present article, we have focused on reactions requiring Lewis-acid sites or redox centers to illustrate the potential applications and limitations of commercial MOFs. In a ¿nal section, we provide our views on future developments whose ultimate target will be the use of a commercial MOF as a heterogeneous catalyst for a real industrial process in ¿ne chemistry, thus, realizing the advantages of these materials with respect to zeolites or other solid catalysts in liquid-phase reactions. | es_ES |
dc.description.sponsorship | Financial support by the Spanish Ministry of Science and Education (Consolider MULTICAT, CTQ-2010-18671 and CTQ-2012-32315) are gratefully acknowledged. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Chemical Communications | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Commercial metal-organic frameworks as heterogeneous catalysts | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1039/c2cc34329k | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CTQ2010-18671/ES/APLICACION DE SOLIDOS RETICULARES METAL-ORGANICO MODIFICADOS COMO CATALIZADORES HETEROGENEOS EN PROCESOS DE OXIDACION AEROBICA Y EN REACCIONES PROMOVIDAS POR ACIDOS DE LEWIS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Amarajothi, D.; Alvaro Rodríguez, MM.; García Gómez, H. (2012). Commercial metal-organic frameworks as heterogeneous catalysts. Chemical Communications. 48(92):11275-11288. https://doi.org/10.1039/c2cc34329k | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c2cc34329k | es_ES |
dc.description.upvformatpinicio | 11275 | es_ES |
dc.description.upvformatpfin | 11288 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 48 | es_ES |
dc.description.issue | 92 | es_ES |
dc.relation.senia | 240438 | |
dc.identifier.eissn | 1364-548X | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |