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Synthesis and Catalytic Properties of Hybrid Mesoporous Materials Assembled from Polyhedral and Bridged Silsesquioxane Monomers

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Synthesis and Catalytic Properties of Hybrid Mesoporous Materials Assembled from Polyhedral and Bridged Silsesquioxane Monomers

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dc.contributor.author Díaz Morales, Urbano Manuel es_ES
dc.contributor.author García Fernández, María Teresa es_ES
dc.contributor.author Velty, Alexandra Isabelle Lucienne es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2013-11-15T08:55:40Z
dc.date.issued 2012-07-09
dc.identifier.issn 0947-6539
dc.identifier.uri http://hdl.handle.net/10251/33615
dc.description.abstract A family of hybrid mesoporous materials with high temperature stability was obtained by the suitable covalent combination of two types of siloxane precursors. Specifically, cubic T8 polyhedral oligomeric (POSS) and aryl bridged silsesquioxane monomers (1,4-bis(triethoxysilyl)benzene, BTEB) play the role of nanobuilders. An optimal molar ratio of the two precursors (5¿25 mol% of total silicon content from the BTEB disilane) generated a homogenous, highly accessible, and well-defined mesoporous material with hexagonal symmetry and narrow pore size distribution. Physicochemical, textural, and spectroscopic analysis corroborated the effective integration and preservation of the two different nanoprecursors, thereby confirming the framework of the mesoporous hybrid materials. A post-synthesis amination treatment allowed the effective incorporation of amino groups onto the aryl linkers, thereby obtaining a stable and recyclable basic catalyst for use in C C bond-formation processes. es_ES
dc.description.sponsorship The authors thank the Spanish MICINN (Consolider Ingenio 2010-MUL-TICAT (CSD2009-00050) and MAT2011-29020-C02-01) for their financial support. T. G. thanks the CSIC for the award of a JAE pre-doctoral fellowship. en_EN
dc.format.extent 14 es_ES
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Amination es_ES
dc.subject Condensation reactions es_ES
dc.subject Mesoporous materials es_ES
dc.subject Silsesquioxanes es_ES
dc.subject Organic - inorganic hybrid composites es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Synthesis and Catalytic Properties of Hybrid Mesoporous Materials Assembled from Polyhedral and Bridged Silsesquioxane Monomers es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/chem.201200170
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2011-29020-C02-01/ES/CATALIZADORES HIBRIDOS MULTIFUNCIONALES BASADOS EN UNIDADES ESTRUCTURALES ORGANICAS-INORGANICAS UTILIZADOS EN REACCIONES CASCADA/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Díaz Morales, UM.; Garcia Fernandez, MT.; Velty, AIL.; Corma Canós, A. (2012). Synthesis and Catalytic Properties of Hybrid Mesoporous Materials Assembled from Polyhedral and Bridged Silsesquioxane Monomers. Chemistry - A European Journal. 18(28):8659-8672. doi:10.1002/chem.201200170 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/chem.201200170 es_ES
dc.description.upvformatpinicio 8659 es_ES
dc.description.upvformatpfin 8672 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 18 es_ES
dc.description.issue 28 es_ES
dc.relation.senia 236227
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
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