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dc.contributor.author | Barskiy, Danila A | es_ES |
dc.contributor.author | Kovtunov, Kirill V. | es_ES |
dc.contributor.author | Primo Arnau, Ana María | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.contributor.author | Kaptein, Robert | es_ES |
dc.contributor.author | Koptyug, Igor V | es_ES |
dc.date.accessioned | 2013-11-26T08:06:12Z | |
dc.date.issued | 2012-12 | |
dc.identifier.issn | 1867-3880 | |
dc.identifier.uri | http://hdl.handle.net/10251/33991 | |
dc.description.abstract | [EN] Hydrogenation of 1,3-butadiene and 1-butyne over the Rh/chitosan catalyst in gaseous and liquid phases was investigated by using the NMR and parahydrogen-induced polarization technique. The Rh/chitosan system was a very selective catalyst for the partial hydrogenation of 1,3-butadiene and 1-butyne to 1- and 2-butenes. The catalyst demonstrated high activity in the hydrogenation of 1-butyne after its activation in the hydrogenation of 1,3-butadiene. Therefore, the Rh/chitosan catalyst was used for the catalytic removal of 1,3-butadiene and 1-butyne from gaseous butene streams. Moreover, the syn- and anti-addition of the hydrogen molecule to substrates proceeded in a pairwise manner in the gas phase heterogeneous hydrogenation as was demonstrated by parahydrogen-induced polarization. However, in the liquid phase hydrogenation of 1-butyne, both hydrogen atoms from the same hydrogen molecule were added to 1-butyne only through the syn-addition route. | es_ES |
dc.description.sponsorship | This work was partially supported by grants RFBR 11-03-93995-CSIC a, RFBR 11-03-00248-a, RFBR 12-03-00403-a, RAS (5.1.1), and SB RAS (#60, 61, 57, 122); by the program of support of leading scientific schools (NSh-2429.2012.3); and by the program of the Russian Government to support leading scientists (11.G34.31.0045). | |
dc.format.extent | 6 | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Wiley-VCH Verlag | es_ES |
dc.relation.ispartof | ChemCatChem | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Chitosan | es_ES |
dc.subject | Heterogeneous | es_ES |
dc.subject | Hydrogenation | es_ES |
dc.subject | Parahydrogen-induced polarization | es_ES |
dc.subject | Rhodium | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Selective hydrogenation of 1,3-butadiene and 1-butyne over a Rh/chitosan catalyst investigated by using parahydrogen-induced polarization | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.1002/cctc.201200414 | |
dc.relation.projectID | info:eu-repo/grantAgreement/RFBR//11-03-93995-CSIC a/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/SB RAS//60/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/RFBR//NSh-2429.2012.3/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/RFBR//11.G34.31.0045/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/RFBR//11-03-00248-a/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/RFBR//12-03-00403-a/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/SB RAS//61/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/SB RAS//122/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/SB RAS//57/ | |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Barskiy, DA.; Kovtunov, KV.; Primo Arnau, AM.; Corma Canós, A.; Kaptein, R.; Koptyug, IV. (2012). Selective hydrogenation of 1,3-butadiene and 1-butyne over a Rh/chitosan catalyst investigated by using parahydrogen-induced polarization. ChemCatChem. 4:1-6. https://doi.org/10.1002/cctc.201200414 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/cctc.201200414 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 6 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 4 | es_ES |
dc.relation.senia | 229706 | |
dc.contributor.funder | Russian Foundation for Basic Research | |
dc.contributor.funder | Siberian Branch of the Russian Academy of Sciences | es_ES |