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Identification of Active Surface Species for Friedel Crafts Acylation and Koch Carbonylation Reactions by in situ Solid-State NMR Spectroscopy

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Identification of Active Surface Species for Friedel Crafts Acylation and Koch Carbonylation Reactions by in situ Solid-State NMR Spectroscopy

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dc.contributor.author Lezcano González, Inés es_ES
dc.contributor.author Vidal Moya, José Alejandro es_ES
dc.contributor.author Boronat Zaragoza, Mercedes es_ES
dc.contributor.author Blasco Lanzuela, Teresa es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2015-02-17T11:10:49Z
dc.date.issued 2013-05-03
dc.identifier.issn 1433-7851
dc.identifier.uri http://hdl.handle.net/10251/47186
dc.description.abstract Finding the culprits: In situ NMR spectroscopy combined with theoretical calculations show the formation of acetyl species covalently bound to framework oxygen atoms in acid zeolites. These species, and not the usually assumed acylium cations, are the reactive intermediates in Friedel–Crafts acylation and Koch carbonylation reactions on zeolites. es_ES
dc.description.sponsorship The authors acknowledge Spanish MINECO (Projects MAT-2012-38567-C02-01, CTQ-2012-37925-C03-01 and Consolider Ingenio 2010-MULTICAT, CSD2009-00050). en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Acid catalysts es_ES
dc.subject Density functional theory; es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject NMR spectroscopy es_ES
dc.subject Zeolites es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Identification of Active Surface Species for Friedel Crafts Acylation and Koch Carbonylation Reactions by in situ Solid-State NMR Spectroscopy es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/anie.201209907
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2012-38567-C02-01/ES/MATERIALES ZEOLITICOS COMO ESTRUCTURAS ANFITRIONAS DE NANOPARTICULAS. SINTESIS Y APLICACIONES NANOTECNOLOGICAS, CATALITICAS Y MEDIOAMBIENTALES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-37925-C03-01/ES/CATALIZADORES PARA LA ENERGIA Y EL MEDIOAMBIENTE: ACTIVACION SELECTIVA DE ENLACES S-H Y C-H/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Lezcano González, I.; Vidal Moya, JA.; Boronat Zaragoza, M.; Blasco Lanzuela, T.; Corma Canós, A. (2013). Identification of Active Surface Species for Friedel Crafts Acylation and Koch Carbonylation Reactions by in situ Solid-State NMR Spectroscopy. Angewandte Chemie International Edition. 52(19):5138-5141. doi:10.1002/anie.201209907 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1002/anie.201209907 es_ES
dc.description.upvformatpinicio 5138 es_ES
dc.description.upvformatpfin 5141 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 52 es_ES
dc.description.issue 19 es_ES
dc.relation.senia 257707
dc.identifier.eissn 1521-3773
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