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dc.contributor.author | Dhakshinamoorthy, Amarajothi | es_ES |
dc.contributor.author | Alvaro Rodríguez, Maria Mercedes | es_ES |
dc.contributor.author | Concepción Heydorn, Patricia | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.date.accessioned | 2015-03-11T12:59:36Z | |
dc.date.available | 2015-03-11T12:59:36Z | |
dc.date.issued | 2011-06-10 | |
dc.identifier.issn | 1566-7367 | |
dc.identifier.uri | http://hdl.handle.net/10251/47991 | |
dc.description.abstract | In contrast to Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate), the crystal structure of Cu3(BTC)2, a commercial metal organic framework widely used as solid catalyst, collapses when contacted with thiols under mild reaction conditions forming copper nanoparticles. | es_ES |
dc.description.sponsorship | Financial support by the Spanish DGI (CTQ2009-11587 and CTQ2010-18671) is gratefully acknowledged. Maykel de Miguel is thanked for helping to record TEM images. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Catalysis Communications | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Cu3(BTC)2 | es_ES |
dc.subject | Copper | es_ES |
dc.subject | Metal organic frameworks | es_ES |
dc.subject | Thiols | es_ES |
dc.subject | Metal nanoparticles | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Chemical instability of Cu(3)(BTC)(2) by reaction with thiols | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.catcom.2011.03.018 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CTQ2010-18671/ES/APLICACION DE SOLIDOS RETICULARES METAL-ORGANICO MODIFICADOS COMO CATALIZADORES HETEROGENEOS EN PROCESOS DE OXIDACION AEROBICA Y EN REACCIONES PROMOVIDAS POR ACIDOS DE LEWIS/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Dhakshinamoorthy, A.; Alvaro Rodríguez, MM.; Concepción Heydorn, P.; García Gómez, H. (2011). Chemical instability of Cu(3)(BTC)(2) by reaction with thiols. Catalysis Communications. 12(11):1018-1021. https://doi.org/10.1016/j.catcom.2011.03.018 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.catcom.2011.03.018 | es_ES |
dc.description.upvformatpinicio | 1018 | es_ES |
dc.description.upvformatpfin | 1021 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 12 | es_ES |
dc.description.issue | 11 | es_ES |
dc.relation.senia | 215878 | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |