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Properties of Biobased Epoxy Resins from Epoxidized Soybean Oil (ESBO) Cured with Maleic Anhydride (MA)

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Properties of Biobased Epoxy Resins from Epoxidized Soybean Oil (ESBO) Cured with Maleic Anhydride (MA)

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dc.contributor.author España Giner, José Manuel es_ES
dc.contributor.author Sánchez Nacher, Lourdes es_ES
dc.contributor.author Boronat Vitoria, Teodomiro es_ES
dc.contributor.author Fombuena Borrás, Vicent es_ES
dc.contributor.author Balart Gimeno, Rafael Antonio es_ES
dc.date.accessioned 2015-05-19T10:13:12Z
dc.date.available 2015-05-19T10:13:12Z
dc.date.issued 2012-11
dc.identifier.issn 0003-021X
dc.identifier.uri http://hdl.handle.net/10251/50460
dc.description.abstract [EN] Epoxidized soybean oil (ESBO), obtained from a renewable resource was used in the production of thermoset resins. Samples of the ESBO were initially treated with maleic anhydride, equal mixture of catalyst (1,3-butanediol anhydrous and benzyldimethylamine) and the mixture was cured for 5 h at different temperatures. After the curing process, the ratio between the ESBO and the anhydride (ratio EEW:AEW) was evaluated in terms of the different mechanical properties produced using flexural, Shore D hardness and Charpy impact tests. The sample with the best mechanical properties was that with an EEW:AEW ratio of 1:1.0 which leads to best balanced behavior and this could be representative for the maximum crosslinking degree. Also, thermal characteristics were evaluated during the crosslinking process using differential scanning calorimetry, In addition, other thermal characteristics of the cured materials were obtained by determining the heat deflection temperature and the Vicat softening temperature. The coefficient of thermal expansion was determined using thermo-mechanical analysis. In accordance with the mechanical behavior, the best thermal properties were obtained for samples with an EEW:AEW ratio of 1:1.0. As a result of this work, a biologically based epoxy resin with good mechanical properties and flexibility was obtained. © AOCS 2012. es_ES
dc.description.sponsorship This research is part of the IPT-310000-2010-037, "ECOTEXCOMP: research and development of textile structures applicable as reinforcement in compound materials of an ecological nature" project, financed by the Ministry of Science and Innovation, with a grant of 189,540.20 EUR, as part of the National Scientific Research, Development and Technological Innovation 2008-2011 plan, co-financed by the European Union through FEDER, Technology fund 2007-2013, Operative Program of R and D to benefit companies. J. M. Espana gives thanks to the Polytechnic University of Valencia (UPV) for their financial support through an FPI-UPV grant.
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation MICINN/189,540.20 EUR es_ES
dc.relation.ispartof Journal of the American Oil Chemists' Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Biobased products es_ES
dc.subject Coatings es_ES
dc.subject Fat and oil es_ES
dc.subject Polymers es_ES
dc.subject Vegetable oilseed es_ES
dc.subject Bio-based products es_ES
dc.subject Biobased epoxy es_ES
dc.subject Charpy impact tests es_ES
dc.subject Cross-linking degree es_ES
dc.subject Cross-linking process es_ES
dc.subject Cured materials es_ES
dc.subject Curing process es_ES
dc.subject Epoxidized soybean oil es_ES
dc.subject Heat deflection temperature es_ES
dc.subject Mechanical behavior es_ES
dc.subject Renewable resource es_ES
dc.subject Shore D-hardness es_ES
dc.subject Thermal characteristics es_ES
dc.subject Thermo-mechanical analysis es_ES
dc.subject Thermoset resin es_ES
dc.subject Vicat softening temperature es_ES
dc.subject Curing es_ES
dc.subject Differential scanning calorimetry es_ES
dc.subject Epoxy resins es_ES
dc.subject Maleic anhydride es_ES
dc.subject Mechanical properties es_ES
dc.subject Oilseeds es_ES
dc.subject Thermosets es_ES
dc.subject Resins es_ES
dc.subject Glycine max es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.subject.classification INGENIERIA MECANICA es_ES
dc.title Properties of Biobased Epoxy Resins from Epoxidized Soybean Oil (ESBO) Cured with Maleic Anhydride (MA) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s11746-012-2102-2
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation España Giner, JM.; Sánchez Nacher, L.; Boronat Vitoria, T.; Fombuena Borrás, V.; Balart Gimeno, RA. (2012). Properties of Biobased Epoxy Resins from Epoxidized Soybean Oil (ESBO) Cured with Maleic Anhydride (MA). Journal of the American Oil Chemists' Society. 89(11):2067-2075. doi:10.1007/s11746-012-2102-2 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s11746-012-2102-2 es_ES
dc.description.upvformatpinicio 2067 es_ES
dc.description.upvformatpfin 2075 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 89 es_ES
dc.description.issue 11 es_ES
dc.relation.senia 230519
dc.identifier.eissn 1558-9331
dc.contributor.funder Ministerio de Ciencia e Innovación
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