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Photoinduced chemiluminescence determination of carbamate pesticides

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Photoinduced chemiluminescence determination of carbamate pesticides

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dc.contributor.author Catalá-Icardo, Mónica es_ES
dc.contributor.author Meseguer-Lloret, S. es_ES
dc.contributor.author Torres-Cartas, Sagrario es_ES
dc.date.accessioned 2016-06-02T17:00:48Z
dc.date.available 2016-06-02T17:00:48Z
dc.date.issued 2016-04
dc.identifier.issn 1474-905X
dc.identifier.uri http://hdl.handle.net/10251/65133
dc.description.abstract A liquid chromatography method with post-column photoinduced chemiluminescence (PICL) detection is proposed for the simultaneous determination of eight carbamate pesticides, namely aldicarb, butocarboxim, ethiofencarb, methomyl, methiocarb, thiodicarb, thiofanox and thiophanate-methyl. After chromatographic separation, quinine (sensitizer) was incorporated and the flow passed through an UV lamp (67 s of irradiation time) to obtain the photoproducts, which reacted with acidic Ce(IV) and provided a CL emission. The PICL method showed great selectivity for carbamate pesticides containing sulphur in their chemical structure. A solid-phase extraction process increased sensitivity (LODs ranging from 0.06 to 0.27 ng mL−1) and allowed the carbamate pesticides in surface and ground water samples to be determined, with recoveries in the range 87 110% (except for thiophanate-methyl, whose recoveries were between 60 and 75%). The intra- and inter-day precision was evaluated, with RSD ranging from 1.1 to 7.5% and from 2.6 to 12.3%, respectively. A discussion about the PICL mechanism is also included. es_ES
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Photochemical and Photobiological Sciences es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Photoinduced chemiluminescence es_ES
dc.subject Carbamate pesticides es_ES
dc.subject HPLC es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Photoinduced chemiluminescence determination of carbamate pesticides es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c6pp00056h
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Investigación para la Gestión Integral de Zonas Costeras - Institut d'Investigació per a la Gestió Integral de Zones Costaneres es_ES
dc.description.bibliographicCitation Catalá-Icardo, M.; Meseguer-Lloret, S.; Torres-Cartas, S. (2016). Photoinduced chemiluminescence determination of carbamate pesticides. Photochemical and Photobiological Sciences. 15:626-634. doi:10.1039/c6pp00056h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c6pp00056h es_ES
dc.description.upvformatpinicio 626 es_ES
dc.description.upvformatpfin 634 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 15 es_ES
dc.relation.senia 312211 es_ES
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