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Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions

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Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions

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dc.contributor.author Oliver Meseguer, Judit es_ES
dc.contributor.author Liu, Lichen es_ES
dc.contributor.author García García, Saray es_ES
dc.contributor.author Canós Giménez, Clàudia es_ES
dc.contributor.author Domínguez Pérez, Irene es_ES
dc.contributor.author GAVARA CLEMENTE, RAFAEL es_ES
dc.contributor.author Domenech Carbo, Antonio es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2016-06-13T06:56:55Z
dc.date.issued 2015-03-25
dc.identifier.issn 0002-7863
dc.identifier.uri http://hdl.handle.net/10251/65695
dc.description This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [insert ACS Articles on Request author-directed link to Published Work, see http://pubs.acs.org/doi/abs/10.1021%2Fjacs.5b00222 Additional Figures S1−S20, experimental procedures, and compound characterization, including NMR spectra. This material is available free of charge via the Internet at http:// pubs.acs.org. es_ES
dc.description.abstract [EN] Sub-nanometric Cu clusters formed by endogenous reduction of Cu salts and Cu nanoparticles are active and selective catalysts for C−N, C−C, C−O, C−S, and C−P bond-forming reactions. Sub-nanometric Cu clusters have also been generated within a polymeric film and stored with full stability for months. In this way, they are ready to be used on demand and maintain high activity (TONs up to 104 ) and selectivity for the above reactions. A potential mechanism for the formation of the sub-nanometric clusters and their electronic nature is presented. es_ES
dc.description.sponsorship Financial support by the Severo-Ochoa program, Consolider-Ingenio 2010 (proyecto MULTICAT), and PLE2009 project from MCIINN is acknowledged. J.O.-M., L.-L., and A.L.-P. thank ITQ for the concession of a contract. I.D. and R.G. thank the Spanish Ministry of Science and Innovation for financial support through project AGL-2012-39920-C03-01. I.D. thanks the CSIC for the postdoctoral contract concession (JAE-DOC). en_EN
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Journal of the American Chemical Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject CROSS-COUPLING REACTIONS es_ES
dc.subject HETEROGENEOUS CATALYSIS es_ES
dc.subject GOLD CLUSTERS es_ES
dc.subject ARYL HALIDES es_ES
dc.subject DIAMINE LIGANDS es_ES
dc.subject COPPER CLUSTERS es_ES
dc.subject ULLMANN es_ES
dc.subject TEMPERATURE es_ES
dc.subject MECHANISMS es_ES
dc.subject Oxidation es_ES
dc.subject.classification TECNOLOGIA DE ALIMENTOS es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/jacs.5b00222
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//AGL2012-39920-C03-01/ES/NUEVOS SISTEMAS POLIMERICOS ACTIVOS PARA EL ENVASADO DE ALIMENTOS SENSIBLES AL DETERIORO MICROBIOLOGICO Y OXIDATIVO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ / es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Tecnología de Alimentos - Departament de Tecnologia d'Aliments es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Oliver Meseguer, J.; Liu, L.; García García, S.; Canós Giménez, C.; Domínguez Pérez, I.; Gavara Clemente, R.; Domenech Carbo, A.... (2015). Stabilized Naked Sub-nanometric Cu Clusters within a Polymeric Film Catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions. Journal of the American Chemical Society. 137(11):3894-3900. https://doi.org/10.1021/jacs.5b00222 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://dx.doi.org/10.1021/jacs.5b00222 es_ES
dc.description.upvformatpinicio 3894 es_ES
dc.description.upvformatpfin 3900 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 137 es_ES
dc.description.issue 11 es_ES
dc.relation.senia 296847 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Instituto de Tecnología Química UPV-CSIC es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES


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