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Hybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blocks

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Hybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blocks

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Nombre: Gianotti, E. et al. ...
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Nombre: Corma;DÍAZ;GIANOTTI ...
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dc.contributor.author Gianotti, Enrica es_ES
dc.contributor.author Díaz Morales, Urbano Manuel es_ES
dc.contributor.author Coluccia, Salvatore es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2016-06-20T10:13:03Z
dc.date.available 2016-06-20T10:13:03Z
dc.date.issued 2011
dc.identifier.issn 1463-9076
dc.identifier.uri http://hdl.handle.net/10251/66163
dc.description.abstract [EN] Non-ordered organic-inorganic mesoporous hybrid materials with basic sites have been synthesized following a fluoride-catalysed sol-gel process at neutral pH and low temperatures that avoids the use of structural directing agents (SDAs). Proton sponges have been used as the organic builder of the hybrids, while the inorganic part corresponds to silica tetrahedra. The proton sponges are diamines that exhibit very high basicity and, after functionalization, have been introduced as part of the walls of the mesoporous silica by one-pot synthesis. Several hybrids with different organic loadings have been synthesized and characterized by gas adsorption, thermogravimetric and elemental analysis, solid state MAS-NMR and FTIR spectroscopy. These hybrids show high activity as base catalysts and can be recycled. es_ES
dc.description.sponsorship The authors thank financial support by Consolider-Ingenio (MULTICAT project) from Spanish Government. EG thanks Marie Curie Fellowship (FP7-PEOPLE-2009-IEF) for financial support. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Physical Chemistry Chemical Physics es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Hybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blocks es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c1cp20588a
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/252367/EU/Decomposition of Structured Tensors, Algorithms and Characterization./
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Gianotti, E.; Díaz Morales, UM.; Coluccia, S.; Corma Canós, A. (2011). Hybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blocks. Physical Chemistry Chemical Physics. 13(24):11702-11709. https://doi.org/10.1039/c1cp20588a es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c1cp20588a es_ES
dc.description.upvformatpinicio 11702 es_ES
dc.description.upvformatpfin 11709 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 13 es_ES
dc.description.issue 24 es_ES
dc.relation.senia 209014 es_ES
dc.contributor.funder European Commission
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