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dc.contributor.author | Borrás García, Esther Mª | es_ES |
dc.contributor.author | Tortajada-Genaro, Luis Antonio | es_ES |
dc.contributor.author | Muñoz, Amalia | es_ES |
dc.date.accessioned | 2016-07-01T11:01:08Z | |
dc.date.available | 2016-07-01T11:01:08Z | |
dc.date.issued | 2016-02-01 | |
dc.identifier.issn | 0039-9140 | |
dc.identifier.uri | http://hdl.handle.net/10251/66922 | |
dc.description.abstract | [EN] A reliable method to det. odorous reduced S compds. (RSC) in air was developed. This method uses an activated coconut solid-phase sorbent for active sampling, hexane as desorption solvent, and gas chromatog./mass spectrometry (GC/MS) for specific and sensitive sepn.-detection. Analyzed compds. were H2S, Et mercaptan, di-Me sulfide, CS2, Bu mercaptan, di-Me disulfide. Recovery efficiency was 75-97%; no detectable losses were obsd. during storage at -20°. Satisfactory anal. parameters were reported: good linearity (r2 >0.98), low detection limits (0.6-59 pg/m3), adequate repeatability (9%) and reproducibility (17%), and fast GC/MS anal. (<6.5 min). Accurate detn. of RSC, free from atm. component interferences (e.g., O3 or water) was demonstrated. The method analyzed the compn. of environmental air near 3 landfills accepting urban and industrial solid wastes. Results indicated H2S and Et mercaptan were the main mols. responsible of odor phenomena in the study areas. | es_ES |
dc.description.sponsorship | The Instituto Universitario CEAM-UMH is partly supported by Generalitat Valenciana, and DESSESTRES (Prometeo - Generalitat Valenciana). We also acknowledged the European Community's Seventh Framework Program under the Grant agreement no. 228335 (Eurochamp2), the Spanish Ministry of Science and Innovation, through INNPLANTA project: PCT-440000-2010-003 and the EUPHORE staff. The authors also thank A.T.B. and S.M. for their contribution. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Talanta | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Gas chromatography-mass spectrometry | es_ES |
dc.subject | Malodor compounds | es_ES |
dc.subject | Reduced sulfur compounds | es_ES |
dc.subject | Solid-phase sampling | es_ES |
dc.subject.classification | QUIMICA ANALITICA | es_ES |
dc.title | Determination of reduced sulfur compounds in air samples for the monitoring of malodor caused by landfills | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.talanta.2015.11.021 | |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/228335/EU/Integration of European Simulation Chambers for Investigating Atmospheric Processes - Part 2/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//PCT-440000-2010-003/ES/ADQUISICION Y MEJORA DE TÉCNICAS INTRUMENTALES PARA LA INVESTIGACIÓN DE LOS PROCESOS QUÍMICOS ATMOSFÉRICOS EN CÁMARAS DE SIMULACIÓN/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Borrás García, EM.; Tortajada-Genaro, LA.; Muñoz, A. (2016). Determination of reduced sulfur compounds in air samples for the monitoring of malodor caused by landfills. Talanta. 148:472-477. https://doi.org/10.1016/j.talanta.2015.11.021 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://dx.doi.org/10.1016/j.talanta.2015.11.021 | es_ES |
dc.description.upvformatpinicio | 472 | es_ES |
dc.description.upvformatpfin | 477 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 148 | es_ES |
dc.relation.senia | 300077 | es_ES |
dc.contributor.funder | Generalitat Valenciana | |
dc.contributor.funder | European Commission | |
dc.contributor.funder | Ministerio de Ciencia e Innovación |