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Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution

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Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution

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dc.contributor.author Li, Zhibin es_ES
dc.contributor.author Martínez Triguero, Luis Joaquín es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author YU, JIHONG es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2016-09-01T11:24:58Z
dc.date.available 2016-09-01T11:24:58Z
dc.date.issued 2013
dc.identifier.issn 1463-9076
dc.identifier.uri http://hdl.handle.net/10251/68532
dc.description.abstract [EN] Nano-SAPO-34 molecular sieves synthesized in a microwave environment with 20 nm crystal size showed a longer lifetime than SAPO-34 prepared by the conventional hydrothermal method in the reaction of methanol to olefins. It has been found that silicon distribution strongly affects the lifetime and selectivity. Thus, silicon at the border of the silicon islands gives a higher lifetime and lower C2/C3 ratio. This change in activity and selectivity is better explained in terms of different silicon distribution than by preferential diffusion of ethene through the 8MR pores and agrees with transition-state selectivity. The effects of equilibrium of olefins and deactivation by coke were isolated, showing that after full formation of the hydrocarbon pool, selectivity is independent of deactivation by coke. es_ES
dc.description.sponsorship Financial support by the Spanish MINECO (MAT2012-37160, CSD2009-00050-CONSOLIDER/INGENIO 2010), and Generalitat Valenciana by the PROMETEO program is acknowledged. Z. Li acknowledges China Scholarship Council (CSC) for a fellowship. J. Yu thanks the support by the State Basic Research Project of China (Grant no. 2011CB808703) and the National Natural Science Foundation of China. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Physical Chemistry Chemical Physics es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject HYDROCARBON POOL MECHANISM es_ES
dc.subject MESOPOROUS SSZ-13 ZEOLITE es_ES
dc.subject MAS NMR-SPECTROSCOPY es_ES
dc.subject SOLID-STATE NMR es_ES
dc.subject MTO-REACTION es_ES
dc.subject CATALYTIC PERFORMANCE es_ES
dc.subject SILICOALUMINOPHOSPHATES H-SAPO-34 es_ES
dc.subject THERMAL-STABILITY es_ES
dc.subject COKE DEPOSITION es_ES
dc.subject TEMPLATE METHOD es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c3cp52247d
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ / es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NKRDPC//2011CB808703/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2012-37160/ES/SINTESIS DE NUEVOS MATERIALES MICROPOROSOS BASADOS EN EL USO DE ?ESPONJAS DE PROTONES? COMO AGENTES DIRECTORES DE ESTRUCTURA (ADES)/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Li, Z.; Martínez Triguero, LJ.; Concepción Heydorn, P.; Yu, J.; Corma Canós, A. (2013). Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution. Physical Chemistry Chemical Physics. 15(35):14670-14680. https://doi.org/10.1039/c3cp52247d es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://dx.doi.org/10.1039/c3cp52247d es_ES
dc.description.upvformatpinicio 14670 es_ES
dc.description.upvformatpfin 14680 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 15 es_ES
dc.description.issue 35 es_ES
dc.relation.senia 258146 es_ES
dc.identifier.eissn 1463-9084
dc.contributor.funder National Key Research and Development Program of China es_ES
dc.contributor.funder China Scholarship Council es_ES
dc.contributor.funder National Natural Science Foundation of China es_ES
dc.contributor.funder Generalitat Valenciana es_ES
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