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dc.contributor.author | Luz Mínguez, Ignacio | es_ES |
dc.contributor.author | Leon Peris, Adela | es_ES |
dc.contributor.author | Boronat Zaragoza, Mercedes | es_ES |
dc.contributor.author | Llabrés i Xamena, Francesc Xavier | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2016-10-04T07:25:12Z | |
dc.date.available | 2016-10-04T07:25:12Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 2044-4753 | |
dc.identifier.uri | http://hdl.handle.net/10251/71077 | |
dc.description.abstract | [EN] MOFs with Cu2+ centers linked to four nitrogen atoms from azaheterocyclic compounds, i.e., pyrimidine [Cu(2-pymo)(2)] and imidazole [Cu(im)(2)], are active catalysts for aerobic oxidation of activated alkanes, such as tetralin, cumene and ethylbenzene. Differences in activity among the two MOFs appear to be related to differences in their ability to decompose the hydroperoxide and to coordinate to the resulting radical (OH)-O-center dot species. Copper ions in [Cu(im)(2)] can coordinate by expanding their coordination sphere from 4 to 5 in a reversible way, while in the case of [Cu(2-pymo)(2)] it results in a displacement of one of the pyrimidine ligands. The MOFs can be used in combination with a silylated Ti-MCM-41 to catalyze the epoxidation of olefins with oxygen by means of a tandem reaction in which the MOF produces cumene hydroperoxide, which is used by Ti-MCM-41 to epoxidize the olefin. | es_ES |
dc.description.sponsorship | Financial support by Ministerio de Educacion y Ciencia e Innovacion (Project MIYCIN, CSD2009-00050; PROGRAMA CONSOLIDER. INGENIO 2009), Generalidad Valenciana (GV PROMETEO/2008/130) and CSIC (Proyectos Intramurales Especiales 201080I020) is gratefully acknowledged. CSIC and Fundacion Bancaja are gratefully acknowledged for a research contract to I.L. AL thanks the ITQ for a postgraduate scholarship. | |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Catalysis Science and Technology | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Metal-organic frameworks | es_ES |
dc.subject | Heterogeneous catalysis | es_ES |
dc.subject | Stability | es_ES |
dc.subject | Tetralin | es_ES |
dc.subject | Polymers | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Selective aerobic oxidation of activated alkanes with MOFs and their use for epoxidation of olefins with oxygen in a tandem reaction | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/C2CY20449E | |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/Generalitat Valenciana//PROMETEO08%2F2008%2F130/ES/Química sostenible: Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas./ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/CSIC//201080I020/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Luz Mínguez, I.; Leon Peris, A.; Boronat Zaragoza, M.; Llabrés I Xamena, FX.; Corma Canós, A. (2013). Selective aerobic oxidation of activated alkanes with MOFs and their use for epoxidation of olefins with oxygen in a tandem reaction. Catalysis Science and Technology. 3(2):371-379. https://doi.org/10.1039/C2CY20449E | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c2cy20449e | es_ES |
dc.description.upvformatpinicio | 371 | es_ES |
dc.description.upvformatpfin | 379 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 3 | es_ES |
dc.description.issue | 2 | es_ES |
dc.relation.senia | 233114 | es_ES |
dc.contributor.funder | Ministerio de Educación y Ciencia e Innovación | |
dc.contributor.funder | Generalitat Valenciana | |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas |