Margarit Benavent, VJ.; Martínez Armero, ME.; Navarro Villalba, MT.; Martínez, C.; Corma Canós, A. (2015). Direct Dual-Template Synthesis of MWW Zeolite Monolayers. Angewandte Chemie International Edition. 54(46):13724-13728. https://doi.org/10.1002/anie.201506822
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/77648
Title:
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Direct Dual-Template Synthesis of MWW Zeolite Monolayers
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Author:
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Margarit Benavent, Vicente Juan
Martínez Armero, Marta Evelia
Navarro Villalba, Mª Teresa
Martínez, Cristina
Corma Canós, Avelino
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UPV Unit:
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Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
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Issued date:
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Abstract:
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A two-dimensional zeolite with the topol. of MWW sheets has been obtained by direct synthesis with a combination of two org. structure-directing agents. The resultant material consists of approx. 70 % single and double ...[+]
A two-dimensional zeolite with the topol. of MWW sheets has been obtained by direct synthesis with a combination of two org. structure-directing agents. The resultant material consists of approx. 70 % single and double layers and displays a well-structured external surface area of about 300 m2 g-1. The delaminated zeolite prepd. by means of this single-step synthetic route has a high delamination degree, and the structural integrity of the MWW layers is well preserved. The new zeolite material displayed excellent activity, selectivity, and stability when used as a catalyst for the alkylation of benzene with propylene and found to be superior to the catalysts that are currently used for producing cumene.
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Subjects:
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alkylation
,
cumene
,
heterogeneous catalysis
,
organic structure-directing agents
,
zeolites
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Copyrigths:
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Reserva de todos los derechos
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Source:
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Angewandte Chemie International Edition. (issn:
1433-7851
) (eissn:
1521-3773
)
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DOI:
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10.1002/anie.201506822
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Publisher:
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Wiley
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Project ID:
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info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/
info:eu-repo/grantAgreement/MINECO//BES-2013-066800/ES/BES-2013-066800/
info:eu-repo/grantAgreement/MINECO//MAT2012-31657/ES/SINTESIS DE ZEOLITAS MEDIANTE AGENTES DIRECTORES DE ESTRUCTURA BASADOS EN ?MIMICOS? DE ESTADOS DE TRANSICION DE REACCIONES DE INTERES INDUSTRIAL/
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Thanks:
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Financial support by the Spanish Government-MINECO through "Severo Ochoa" (SEV 2012-0267), Consolider Ingenio 2010-Multicat, and MAT2012-31657 is acknowledged. M.E.M.-A. thanks MINECO for financial support through a ...[+]
Financial support by the Spanish Government-MINECO through "Severo Ochoa" (SEV 2012-0267), Consolider Ingenio 2010-Multicat, and MAT2012-31657 is acknowledged. M.E.M.-A. thanks MINECO for financial support through a pre-doctoral fellowship (BES-2013-066800).
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Type:
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Artículo
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