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Effect of Gas Atmosphere on Catalytic Behaviour of Zirconia, Ceria and Ceria Zirconia Catalysts in Valeric Acid Ketonization

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Effect of Gas Atmosphere on Catalytic Behaviour of Zirconia, Ceria and Ceria Zirconia Catalysts in Valeric Acid Ketonization

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dc.contributor.author Zaytseva, Yu. A. es_ES
dc.contributor.author Panchenko, V. N. es_ES
dc.contributor.author Simonov, M. N. es_ES
dc.contributor.author Shutilov, A. A. es_ES
dc.contributor.author Zenkovets, G. A. es_ES
dc.contributor.author Renz, Michael es_ES
dc.contributor.author Simakova, I. L. es_ES
dc.contributor.author Parmon, V. N. es_ES
dc.date.accessioned 2017-06-06T06:42:22Z
dc.date.available 2017-06-06T06:42:22Z
dc.date.issued 2013-06
dc.identifier.issn 1022-5528
dc.identifier.uri http://hdl.handle.net/10251/82407
dc.description.abstract [EN] Ketonization of valeric acid, which can be obtained by lignocellulosic biomass conversion, was carried out in a fixed bed flow reactor over ZrO2, 5-20 % CeO2/ZrO2 and CeO2 both under hydrogen and nitrogen stream at 628 K and atmospheric pressure. Regardless gas-carrier 10 wt% CeO2/ZrO2 was found to show higher catalytic activity compared to zirconia per se as well as other ceria modified zirconia while ceria per se exhibited very low catalytic activity. All catalysts provided higher acid conversion in H-2 than in N-2 whereas selectivity to 5-nonanone was insensitive to gas atmosphere. XRD, FTIR, UV-Vis DRS, XPS, HRTEM methods were applied to characterize catalysts in reduced and unreduced states simulating corresponding reaction conditions during acid ketonization. XRD did not reveal any changes in zirconia and ceria/zirconia lattice parameters as well as crystalline phase depending on gas atmosphere while insertion of ceria in zirconia caused notable increase in lattice parameter indicating some distortion of crystalline structure. According to XPS, FTIR and UV-Vis methods, the carrier gas was found to affect catalyst surface composition leading to alteration in Lewis acid sites ratio. Appearance of Zr3+ cations was observed on the ZrO2 surface after hydrogen pretreatment whereas only Zr4+ cations were determined using nitrogen as a gas-carrier. These changes of catalyst's surface cation composition affected corresponding activity in ketonization probably being crucial for reaction mechanism involving metal cations catalytic centers for acid adsorption and COO- stabilization at the initial step. es_ES
dc.description.sponsorship Financial support from the Russian Foundation of Basic Research (RFBR Grant No 11-03-94001-CSIC) is gratefully acknowledged. This work was supported by the Federal Program "Scientific and Educational Cadres of Russia'' (Grant No 2012-1.5-12-000-1013-002). The authors also wish to thank Dr. Evgeniy Gerasimov, Dr. Igor Prosvirin, Dr. Demid Demidov from the Department of Physicochemical Methods at the Boreskov Institute of Catalysis for TEM and XPS measurements.
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Topics in Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Ceria es_ES
dc.subject Zirconia es_ES
dc.subject Ketonization es_ES
dc.subject Effect of gas atmosphere es_ES
dc.subject Valeric acid es_ES
dc.subject Biomass processing es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.title Effect of Gas Atmosphere on Catalytic Behaviour of Zirconia, Ceria and Ceria Zirconia Catalysts in Valeric Acid Ketonization es_ES
dc.type Artículo es_ES
dc.type Comunicación en congreso es_ES
dc.identifier.doi 10.1007/s11244-013-0045-y
dc.relation.projectID info:eu-repo/grantAgreement/RFBR//11-03-94001-CSIC/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/RFBR//2012-1.5-12-000-1013-002/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Zaytseva, YA.; Panchenko, VN.; Simonov, MN.; Shutilov, AA.; Zenkovets, GA.; Renz, M.; Simakova, IL.... (2013). Effect of Gas Atmosphere on Catalytic Behaviour of Zirconia, Ceria and Ceria Zirconia Catalysts in Valeric Acid Ketonization. Topics in Catalysis. 56(9-10):846-855. https://doi.org/10.1007/s11244-013-0045-y es_ES
dc.description.accrualMethod S es_ES
dc.relation.conferencename 15th Nordic Symposium on Catalysis, Mariehamn, land es_ES
dc.relation.conferencedate June 16-18, 2012 es_ES
dc.relation.conferenceplace Mariehamn, Finland es_ES
dc.relation.publisherversion http://doi.org/10.1007/s11244-013-0045-y es_ES
dc.description.upvformatpinicio 846 es_ES
dc.description.upvformatpfin 855 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 56 es_ES
dc.description.issue 9-10 es_ES
dc.relation.senia 259064 es_ES
dc.identifier.eissn 1572-9028
dc.contributor.funder Russian Science Foundation
dc.contributor.funder Russian Foundation for Basic Research es_ES
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