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Electronic Excitation Energy Transfer between Nucleobases of Natural DNA

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Electronic Excitation Energy Transfer between Nucleobases of Natural DNA

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dc.contributor.author Vayá Pérez, Ignacio es_ES
dc.contributor.author Gustavsson, Thomas es_ES
dc.contributor.author Douki, Thierry es_ES
dc.contributor.author Berlin, Yuri es_ES
dc.contributor.author Markovitsi, Dimitra es_ES
dc.date.accessioned 2017-06-30T11:06:58Z
dc.date.issued 2012-07-18
dc.identifier.issn 0002-7863
dc.identifier.uri http://hdl.handle.net/10251/84248
dc.description.abstract [EN] Transfer of the electronic excitation energy in calf thymus DNA is studied by time-resolved fluorescence spectroscopy. The fluorescence anisotropy, after an initial decay starting on the femtosecond time scale, dwindles down to ca. 0.1. The in-plane depolarized fluorescence decays are described by a stretched exponential law. Our observations are consistent with one-dimensional transfer mediated by charge-transfer excited states. es_ES
dc.description.sponsorship The French Agency for Research (ANR-10-BLAN-0809-01), the Conselleria de Educacion-Generalitat Valenciana (VALi+D program to I.V., No. 2010033), and ONR/MURI (Y.B.) are acknowledged for financial support.
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Journal of the American Chemical Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Electronic Excitation Energy Transfer between Nucleobases of Natural DNA es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1021/ja304328g
dc.relation.projectID info:eu-repo/grantAgreement/GVA/VALI+d/APOSTD%2F2010%2F031/ES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ANR//ANR-10-BLAN-0809/FR/Photo-induced energy transfer in methylated DNA helices and its relevance to UV damage : an interactive theoretical-experimental study/DNAexciton/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Vayá Pérez, I.; Gustavsson, T.; Douki, T.; Berlin, Y.; Markovitsi, D. (2012). Electronic Excitation Energy Transfer between Nucleobases of Natural DNA. Journal of the American Chemical Society. 134:11366-11368. doi:10.1021/ja304328g es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1021/ja304328g es_ES
dc.description.upvformatpinicio 11366 es_ES
dc.description.upvformatpfin 11368 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 134 es_ES
dc.relation.senia 233783 es_ES
dc.contributor.funder Agence Nationale de la Recherche, Francia
dc.contributor.funder Generalitat Valenciana


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