Casado, ClaraFernández-Barquín, AnaValencia Valencia, SusanaIrabien, Ángel2020-07-092020-07-092018-06https://riunet.upv.es/handle/10251/147690[EN] In the present work, the effect of zeolite type and topology on CO2 and N-2 permeability using zeolites of different topology (CHA, RHO, and LTA) in the same Si/Al = 5, embedded in poly(trimethylsilyl-1-propyne) (PTMSP) is evaluated with temperature. Several models are compared on the prediction of CO2/N-2 separation performance and then the modified Maxwell models are selected. The CO2 and N-2 permeabilities through these membranes are predicted with an average absolute relative error (AARE) lower than 0.6% taking into account the temperature and zeolite loading and topology on non-idealities such as membrane rigidification, zeolite-polymer compatibility and sieve pore blockage. The evolution of this structure-performance relationship with temperature has also been predicted.Reconocimiento (by)Mixed matrix membranesPoly(trimethylsilyl-1-propyne) (PTMSP)Small-pore zeolites (CHA, RHO, LTA)TemperatureModelingArtículo10.3390/membranes8020032Abierto2077-037529914166PMC6027413