Sorribes-Terrés, IvánLiu, LichenCorma Canós, Avelino2018-04-272018-04-2720172155-5435https://riunet.upv.es/handle/10251/101066This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/acscatal.7b00170[EN] Nanolayered molybdenum disulfide cobalt-promoted materials (Co-Mo-S) have been established as chemoselective catalysts for thehydrogenation of nitroarenes under relatively mild conditions. Co-Mo-S catalysts have been prepared by a one-pot hydrothermal synthesis that allows the formation of unsupported catalysts with a large number of active sites per unit volume. Via application of these catalysts, the hydrogenation of the nitro functionality has been performed selectively in the presence of double and triple bonds, aldehydes, ketones, and carboxylic acid derivative groups, thus affording the corresponding anilines in good to excellent yields. Interestingly, the partial hydrogenation of some dinitroarenes has also been successfully accomplished. In addition, its catalytic performance has been evaluated for the preparation of the bioactive compound paracetamol through a one-pot direct hydrogenative amidation reaction.Reserva de todos los derechosSelective hydrogenationNitroarenesHeterogeneous catalysisFunctionalized anilinesGreen hydrogenation chemistryNanolayered materialsCo-Mo-S catalystsElectron Microscopy Service of the UPVQUIMICA ORGANICAQUIMICA ANALITICAArtículo10.1021/acscatal.7b00170Abierto