Borcuch, A.Rutkowska, M.Marzec, A.Kowalczyk, A.Michalik, M.Moreno, J.M.Díaz, UrbanoChmielarz, L.2021-04-172021-04-172020-05-150920-5861https://riunet.upv.es/handle/10251/165290[EN] In the presented studies an influence of different parameters, such as zeolite sample porosity, form of used iron source ([Fe-3(OAc)(6)O(H2O)(3)](+)oligocations or FeSO4 solutions) and method of iron species deposition (ion-exchange, impregnation), on the catalytic activity in the process of the selective catalytic oxidation of ammonia (NH3-SCO) was studied. Conventional and mesoporous ZSM-5 zeolites, obtained by desilication and modified with iron species, were analysed with respect to their textural, surface and crystalline properties (N-2-sorption, HRTEM, SEM, XRD) as well as the form of introduced Fe species (UV-vis-DRS). Ion-exchange with [Fe-3(OAc)(6)O (H2O)(3)](+) oligocations and impregnation with these oligocations and FeSO4 solutions were found as the most effective methods of the zeolite samples activation for NH3-SCO.Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)Iron aggregationOligocationsIon-exchangeImpregnationMesoporous MFINH3-SCOSelective ammonia oxidation over ZSM-5 zeolite: Impact of catalyst's support porosity and type of deposited iron speciesArtículo10.1016/j.cattod.2019.08.054Abierto