Wild, StefanFickert, MichaelMitrovic, AleksandraLloret, VicentNeiss, ChristianVidal Moya, José AlejandroRivero-Crespo, Miguel ÁngelLeyva Perez, AntonioWerbach, KatharinaPeterlik, HerwigGrabau, MathiasWittkamper, HaikoPapp, ChristianSteinrück, Hans-PeterPichler, ThomasGorling, Andreas2023-05-182023-05-182019-04-161433-7851https://riunet.upv.es/handle/10251/193466This is the peer reviewed version of the following article: Wild, S., Fickert, M., Mitrovic, A., Lloret, V., Neiss, C., Vidal¿Moya, J. A., ... & Hirsch, A. (2019). Lattice opening upon bulk reductive covalent functionalization of black phosphorus. Angewandte Chemie International Edition, 58(17), 5763-5768, which has been published in final form at https://doi.org/10.1002/anie.201811181. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."[EN] The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)Artículo10.1002/anie.201811181Abierto30675972PMC7318246