Jouini, HoudaMejri, ImènePetitto, CarolinaMartinez-Ortigosa, JoaquinVidal Moya, José AlejandroMhamdi, MouradBlasco Lanzuela, TeresaDelahay, Gerard2024-01-242024-01-242018-04https://riunet.upv.es/handle/10251/202108[EN] The selective catalytic reduction (SCR) of NO with NH3 in the presence of O-2 and H2O over a series of Fe and/or Cu-containing ZSM-5 catalysts prepared by solid state ion exchange (SSIE) was investigated. A wide number of experimental techniques (ICP-AES, XRD, HRTEM, Al-27 MAS NMR, NH3-TPD, DRS UV-vis, HTTPR and EPR) have been applied to understand the metal exchange order effect on the composition, texture, structure, acidity and speciation of bimetallic materials. DRS UV-vis, H-2-TPR, EPR and HRTEM experiments conducted on Cu-Fe-ZSM5 and Fe-Cu-ZSM-5 allowed the identification of both isolated and clustered metal species differing in their amount, environment and degree of aggregation leading to a different catalytic behaviour of both catalysts.Reserva de todos los derechosSolid-state ion exchangeSelective catalytic reduction (SCR)NOZSM-5Artículo10.1016/j.micromeso.2017.10.051Abierto1873-3093